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Structure property relations in multicomponent oxide systems with additions of TiO2 and ZrO2 for glaze applications

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Atkinson, I., Teoreanu, Ion, Mocioiu, O. C., Smith, Mark E. and Zaharescu, M. (2010) Structure property relations in multicomponent oxide systems with additions of TiO2 and ZrO2 for glaze applications. In: 12th International Conference on the Physics of Non-Crystalline Solids (PNCS12), Foz do Iguacu, Brazil, 06-09 Sep 2009. Published in: Journal of Non-Crystalline Solids, Vol.356 (No.44-49 Sp. Iss. SI). pp. 2437-2443.

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Official URL: http://dx.doi.org/10.1016/j.jnoncrysol.2010.04.054

Abstract

The influence of the additives (10 wt.% rutile, anatase and zirconia) on the atomic-scale structure and microstructure of a base glaze (60 wt.% feldspar, 15 wt.% quartz, 8 wt.% kaolin, 12 wt.% dolomite and 5 wt.% zinc oxide) is investigated. The morphology and structure of the glazes were determined by Scanning Electron Microscopy, X-ray diffraction, infra-red spectroscopy, as well as Al-27 and Si-29 magic angle spinning (MAS) NMR. Microscopy and X-ray diffraction revealed that the opacity was caused by crystals formed during thermal treatment. Although there are clearly crystalline phases present NMR shows that the heat treated glazes are dominated by the glassy component meaning the opacity is largely conveyed by the added oxide. The relationship between composition, structure and thermal expansion coefficient of the glazes is examined.

Item Type:

Conference Item (Paper)

Subjects:

T Technology > TP Chemical technology

Divisions:

Administration > Vice Chancellor's Office
Faculty of Science > Physics

Library of Congress Subject Headings (LCSH):

Glazes -- Synthesis, Glazes -- Analysis

Journal or Publication Title:

Journal of Non-Crystalline Solids

Publisher:

Elsevier Science BV

ISSN:

0022-3093

Official Date:

1 October 2010

Dates:

Date	Event
1 October 2010	Published

Volume:

Vol.356

Number:

No.44-49 Sp. Iss. SI

Number of Pages:

Page Range:

pp. 2437-2443

Identification Number:

10.1016/j.jnoncrysol.2010.04.054

Status:

Peer Reviewed

Publication Status:

Published

Access rights to Published version:

Restricted or Subscription Access

Funder:

European Commission (EC), Engineering and Physical Sciences Research Council (EPSRC)

Conference Paper Type:

Paper

Title of Event:

12th International Conference on the Physics of Non-Crystalline Solids (PNCS12)

Type of Event:

Conference

Location of Event:

Foz do Iguacu, Brazil

Date(s) of Event:

06-09 Sep 2009

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