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Structure property relations in multicomponent oxide systems with additions of TiO2 and ZrO2 for glaze applications
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Atkinson, I., Teoreanu, Ion, Mocioiu, O. C., Smith, Mark E. and Zaharescu, M. (2010) Structure property relations in multicomponent oxide systems with additions of TiO2 and ZrO2 for glaze applications. In: 12th International Conference on the Physics of Non-Crystalline Solids (PNCS12), Foz do Iguacu, Brazil, 06-09 Sep 2009. Published in: Journal of Non-Crystalline Solids, Vol.356 (No.44-49 Sp. Iss. SI). pp. 2437-2443. doi:10.1016/j.jnoncrysol.2010.04.054 ISSN 0022-3093.
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Official URL: http://dx.doi.org/10.1016/j.jnoncrysol.2010.04.054
Abstract
The influence of the additives (10 wt.% rutile, anatase and zirconia) on the atomic-scale structure and microstructure of a base glaze (60 wt.% feldspar, 15 wt.% quartz, 8 wt.% kaolin, 12 wt.% dolomite and 5 wt.% zinc oxide) is investigated. The morphology and structure of the glazes were determined by Scanning Electron Microscopy, X-ray diffraction, infra-red spectroscopy, as well as Al-27 and Si-29 magic angle spinning (MAS) NMR. Microscopy and X-ray diffraction revealed that the opacity was caused by crystals formed during thermal treatment. Although there are clearly crystalline phases present NMR shows that the heat treated glazes are dominated by the glassy component meaning the opacity is largely conveyed by the added oxide. The relationship between composition, structure and thermal expansion coefficient of the glazes is examined.
Item Type: | Conference Item (Paper) | ||||
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Subjects: | T Technology > TP Chemical technology | ||||
Divisions: | Administration > University Executive Office Faculty of Science, Engineering and Medicine > Science > Physics |
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Library of Congress Subject Headings (LCSH): | Glazes -- Synthesis, Glazes -- Analysis | ||||
Journal or Publication Title: | Journal of Non-Crystalline Solids | ||||
Publisher: | Elsevier Science BV | ||||
ISSN: | 0022-3093 | ||||
Official Date: | 1 October 2010 | ||||
Dates: |
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Volume: | Vol.356 | ||||
Number: | No.44-49 Sp. Iss. SI | ||||
Number of Pages: | 7 | ||||
Page Range: | pp. 2437-2443 | ||||
DOI: | 10.1016/j.jnoncrysol.2010.04.054 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Date of first compliant deposit: | 3 December 2015 | ||||
Date of first compliant Open Access: | 3 December 2015 | ||||
Funder: | European Commission (EC), Engineering and Physical Sciences Research Council (EPSRC) | ||||
Conference Paper Type: | Paper | ||||
Title of Event: | 12th International Conference on the Physics of Non-Crystalline Solids (PNCS12) | ||||
Type of Event: | Conference | ||||
Location of Event: | Foz do Iguacu, Brazil | ||||
Date(s) of Event: | 06-09 Sep 2009 |
Data sourced from Thomson Reuters' Web of Knowledge
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