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Structure property relations in multicomponent oxide systems with additions of TiO2 and ZrO2 for glaze applications

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Atkinson, I., Teoreanu, Ion, Mocioiu, O. C., Smith, Mark E. and Zaharescu, M. (2010) Structure property relations in multicomponent oxide systems with additions of TiO2 and ZrO2 for glaze applications. In: 12th International Conference on the Physics of Non-Crystalline Solids (PNCS12), Foz do Iguacu, Brazil, 06-09 Sep 2009. Published in: Journal of Non-Crystalline Solids, Vol.356 (No.44-49 Sp. Iss. SI). pp. 2437-2443.

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Official URL: http://dx.doi.org/10.1016/j.jnoncrysol.2010.04.054

Abstract

The influence of the additives (10 wt.% rutile, anatase and zirconia) on the atomic-scale structure and microstructure of a base glaze (60 wt.% feldspar, 15 wt.% quartz, 8 wt.% kaolin, 12 wt.% dolomite and 5 wt.% zinc oxide) is investigated. The morphology and structure of the glazes were determined by Scanning Electron Microscopy, X-ray diffraction, infra-red spectroscopy, as well as Al-27 and Si-29 magic angle spinning (MAS) NMR. Microscopy and X-ray diffraction revealed that the opacity was caused by crystals formed during thermal treatment. Although there are clearly crystalline phases present NMR shows that the heat treated glazes are dominated by the glassy component meaning the opacity is largely conveyed by the added oxide. The relationship between composition, structure and thermal expansion coefficient of the glazes is examined.

Item Type:	Conference Item (Paper)
Subjects:	T Technology > TP Chemical technology
Divisions:	Administration > Vice Chancellor's Office Faculty of Science > Physics
Library of Congress Subject Headings (LCSH):	Glazes -- Synthesis, Glazes -- Analysis
Journal or Publication Title:	Journal of Non-Crystalline Solids
Publisher:	Elsevier Science BV
ISSN:	0022-3093
Official Date:	1 October 2010
Volume:	Vol.356
Number:	No.44-49 Sp. Iss. SI
Number of Pages:	7
Page Range:	pp. 2437-2443
Identification Number:	10.1016/j.jnoncrysol.2010.04.054
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	European Commission (EC), Engineering and Physical Sciences Research Council (EPSRC)
Conference Paper Type:	Paper
Title of Event:	12th International Conference on the Physics of Non-Crystalline Solids (PNCS12)
Type of Event:	Conference
Location of Event:	Foz do Iguacu, Brazil
Date(s) of Event:	06-09 Sep 2009
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URI:	http://wrap.warwick.ac.uk/id/eprint/4612