Guillou, Nathalie, Millange, Franck and Walton, Richard I.. (2011) Rapid and reversible formation of a crystalline hydrate of a metal-organic framework containing a tube of hydrogen-bonded water. Chemical Communications, Vol.47 (No.2). pp. 713-715. ISSN 1359-7345

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Abstract

The flexible metal-organic framework MIL-53(Cr) undergoes a dramatic volume expansion upon immersion in water at room temperature to form a crystalline hydrate in which water is held as a hydrogen-bonded tube: the hydration is readily reversible under ambient conditions as shown by time-resolved powder X-ray diffraction.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry Q Science > QP Physiology
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Crystallography, Hydrogen bonding, Hydrates, Hydration
Journal or Publication Title:	Chemical Communications
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date:	2011
Volume:	Vol.47
Number:	No.2
Number of Pages:	3
Page Range:	pp. 713-715
Identification Number:	10.1039/c0cc03882b
Status:	Peer Reviewed
Publication Status:	Published
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URI:	http://wrap.warwick.ac.uk/id/eprint/4625

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