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Rapid and reversible formation of a crystalline hydrate of a metal-organic framework containing a tube of hydrogen-bonded water
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Guillou, Nathalie, Millange, Franck and Walton, Richard I. (2011) Rapid and reversible formation of a crystalline hydrate of a metal-organic framework containing a tube of hydrogen-bonded water. Chemical Communications, Vol.47 (No.2). pp. 713-715. doi:10.1039/c0cc03882b ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/c0cc03882b
Abstract
The flexible metal-organic framework MIL-53(Cr) undergoes a dramatic volume expansion upon immersion in water at room temperature to form a crystalline hydrate in which water is held as a hydrogen-bonded tube: the hydration is readily reversible under ambient conditions as shown by time-resolved powder X-ray diffraction.
| Item Type: | Journal Article | ||||
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| Subjects: | Q Science > QD Chemistry Q Science > QP Physiology |
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| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Crystallography, Hydrogen bonding, Hydrates, Hydration | ||||
| Journal or Publication Title: | Chemical Communications | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1359-7345 | ||||
| Official Date: | 2011 | ||||
| Dates: |
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| Volume: | Vol.47 | ||||
| Number: | No.2 | ||||
| Number of Pages: | 3 | ||||
| Page Range: | pp. 713-715 | ||||
| DOI: | 10.1039/c0cc03882b | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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