Cui, Xianjin, Liu, Xianping, Tatton, Andrew S., Brown, Steven P., Ye, Haitao and Marsh, Andrew. (2012) Nanodiamond promotes surfactant-mediated triglyceride removal from a hydrophobic surface at or below room temperature. ACS Applied Materials & Interfaces, Vol.4 (No.6). pp. 3225-3232. ISSN 1944-8244

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Abstract

We demonstrate that ca. 5 nm nanodiamond particles dramatically improve triglyceride lipid removal from a hydrophobic surface at room temperature using either anionic or non-ionic surfactants. We prepare nanodiamond–surfactant colloids, measure their stability by dynamic light scattering and use quartz crystal microbalance–dissipation, a technique sensitive to surface mass, in order to compare their ability to remove surface– bound model triglyceride lipid with ionic and non-ionic aqueous surfactants at 15–25 °C. Oxidized, reduced, ω-alkylcarboxylic acid and ω-alkylamidoamine surface-modified adducts are prepared, and then characterized by techniques including 13C cross polarisation (CP) magic-angle spinning (MAS) NMR. Clear improvement in removal of triglyceride was observed in the presence of nanodiamond, even at 15 °C, both with nanodiamond – surfactant colloids, and by prior nanoparticle deposition on interfacial lipid, showing that nanodiamonds are playing a crucial role in the enhancement of the detergency process, providing unique leads in the development of new approaches to low temperature cleaning.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry Faculty of Science > Engineering Faculty of Science > Physics
Library of Congress Subject Headings (LCSH):	Nanodiamonds, Detergents, Cleaning
Journal or Publication Title:	ACS Applied Materials & Interfaces
Publisher:	American Chemical Society
ISSN:	1944-8244
Date:	27 June 2012
Volume:	Vol.4
Number:	No.6
Page Range:	pp. 3225-3232
Identification Number:	10.1021/am300560z
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Engineering and Physical Sciences Research Council (EPSRC), Procter & Gamble Company, Advantage West Midlands (AWM), European Regional Development Fund (ERDF), GlaxoSmithKline, Birmingham Science City
Grant number:	EP/H034269/1 (EPSRC)
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URI:	http://wrap.warwick.ac.uk/id/eprint/46416

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