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Evidence for a non-rhombohedral average structure in the lead-free piezoelectric material Na(0.5)Bi(0.5)TiO(3)

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Gorfman, S. and Thomas, Pam A. (2010) Evidence for a non-rhombohedral average structure in the lead-free piezoelectric material Na(0.5)Bi(0.5)TiO(3). Journal of Applied Crystallography, Vol.43 (No.Part 6). pp. 1409-1414. doi:10.1107/S002188981003342X ISSN 0021-8898.

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Official URL: http://dx.doi.org/10.1107/S002188981003342X

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Abstract

The potential lead-free piezoelectric material sodium bismuth titanate, Na0.5Bi0.5TiO3, was investigated by means of high-resolution single-crystal X-ray diffractometry. The splitting of Bragg peaks observed in the high-resolution reciprocal-space maps suggests that the average structure of Na0.5Bi0.5TiO3 has lower than rhombohedral symmetry. This observation is contrary to the commonly adopted model, which has followed from many previous analyses of neutron and X-ray powder diffraction data.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Engineering and Medicine > Science > Physics
Journal or Publication Title: Journal of Applied Crystallography
Publisher: Wiley-Blackwell Publishing Ltd.
ISSN: 0021-8898
Official Date: December 2010
Dates:
DateEvent
December 2010Published
Volume: Vol.43
Number: No.Part 6
Number of Pages: 6
Page Range: pp. 1409-1414
DOI: 10.1107/S002188981003342X
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Engineering and Physical Sciences Research Council (EPSRC), Advantage West Midlands (AWM), European Regional Development Fund (ERDF)

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