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Single crystal study of competing rhombohedral and monoclinic order in lead zirconate titanate

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Phelan, D., Long, X., Xie, Y., Ye, Z. -G., Glazer, A. M. (Anthony Michael), Yokota, H., Thomas, Pam A. and Gehring, P. M. (2010) Single crystal study of competing rhombohedral and monoclinic order in lead zirconate titanate. Physical Review Letters, Vol.105 (No.20). Article: 207601. doi:10.1103/PhysRevLett.105.207601

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Official URL: http://dx.doi.org/10.1103/PhysRevLett.105.207601

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Abstract

Neutron diffraction data obtained on single crystals of PbZr1-xTixO3 with x = 0.325 and x = 0.460, which lie on the pseudorhombohedral side of the morphotropic phase boundary, suggest a coexistence of rhombohedral (R3m/R3c) and monoclinic (Cm) domains and that monoclinic order is enhanced by Ti substitution. A monoclinic phase with a doubled unit cell (Cc) is ruled out as the ground state.

Item Type: Journal Article
Subjects: Q Science > QC Physics
Divisions: Faculty of Science > Physics
Journal or Publication Title: Physical Review Letters
Publisher: American Physical Society
ISSN: 0031-9007
Official Date: 12 November 2010
Dates:
DateEvent
12 November 2010Published
Volume: Vol.105
Number: No.20
Number of Pages: 4
Page Range: Article: 207601
DOI: 10.1103/PhysRevLett.105.207601
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Engineering and Physical Sciences Research Council (EPSRC), National Science Foundation (NSF), U.S. Office of Naval Research, NSF
Grant number: N00014-06-1-0166, DMR-0944772

Data sourced from Thomson Reuters' Web of Knowledge

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