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Volume-based thermoelasticity: consequences of the (near) proportionality of isothermal compressibility to formula-unit volume
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Jenkins, H. Donald Brooke, Glasser, Leslie and Lee, Joe (2010) Volume-based thermoelasticity: consequences of the (near) proportionality of isothermal compressibility to formula-unit volume. Inorganic Chemistry, Vol.49 (No.21). pp. 9978-9984. doi:10.1021/ic101398g ISSN 0020-1669.
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Official URL: http://dx.doi.org/10.1021/ic101398g
Abstract
Groups of structurally related materials, including the alkali halides, exhibit a proportionality of isothermal compressibility to formula-unit volume. The relationship has recently been explored by Glasser and by Redo et al. In this paper, we present the consequences of such proportionality on the relationships of Born-Lande and Born-Mayer parameters to the formula-unit volume. These relationships have then been tested separately on (i) alkali (excluding cesium) halides and (ii) cesium halides. We conclude that the equations fit the NaCl-type materials satisfactorily, but less well for the CsCl-type materials, and that the Born-Mayer equation is more applicable. These results confirm the conclusion that volume is intimately linked to thermodynamic quantities, as already demonstrated by our development of volume-based thermodynamics (VBT).
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Journal or Publication Title: | Inorganic Chemistry | ||||
Publisher: | American Chemical Society | ||||
ISSN: | 0020-1669 | ||||
Official Date: | 1 November 2010 | ||||
Dates: |
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Volume: | Vol.49 | ||||
Number: | No.21 | ||||
Number of Pages: | 7 | ||||
Page Range: | pp. 9978-9984 | ||||
DOI: | 10.1021/ic101398g | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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