Dynamic HPLC study of C-70 chlorination reveals a surprisingly selective synthesis of C70Cl8
Kuvychko, Igor V., Popov, Alexey A., Streletskii, Alexey V., Nye, Leanne C., Drewello, Thomas, Strauss, Steven H. and Boltalina, Olga V.. (2010) Dynamic HPLC study of C-70 chlorination reveals a surprisingly selective synthesis of C70Cl8. Chemical Communications, Vol.46 (No.43). pp. 8204-8206. ISSN 1359-7345Full text not available from this repository.
Official URL: http://dx.doi.org/10.1039/c0cc03134h
A dynamic HPLC study of C-70 chlorination led to the discovery, isolation, characterization, and development of the efficient preparatory procedures for two previously unknown soluble chlorofullerenes C70Cl8 and C70Cl6 and for insoluble [C70Cl8](n). A novel synthesis of 99% pure C70Cl10 with a nearly quantitative yield was also developed. The first stability study of C70Cl10,8,6 in solution showed that these compounds are very light-sensitive.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculty of Science > Chemistry|
|Journal or Publication Title:||Chemical Communications|
|Publisher:||Royal Society of Chemistry|
|Number of Pages:||3|
|Page Range:||pp. 8204-8206|
|Access rights to Published version:||Restricted or Subscription Access|
|Funder:||Alexander von Humboldt Foundation, U.S. NSF, Colorado State University Research Foundation|
|Grant number:||CHE-0707223, CHE-1012468|
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