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Applications of N '-alkylated derivatives of TsDPEN in the asymmetric transfer hydrogenation of C=O and C=N bonds

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Martins, Jose E. D., Redondo, Miguel A. Contreras and Wills, Martin (2010) Applications of N '-alkylated derivatives of TsDPEN in the asymmetric transfer hydrogenation of C=O and C=N bonds. Tetrahedron: Asymmetry, Vol.21 (No.18). pp. 2258-2264. doi:10.1016/j.tetasy.2010.07.013

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Official URL: http://dx.doi.org/10.1016/j.tetasy.2010.07.013

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Abstract

Arene/Ru(II) complexes of (R,R)-N-alkyl-TsDPEN ligands are effective in the asymmetric transfer hydrogenation of ketones and imines in formic acid/triethylamine solution. The complex derived from the N'-Bn derivative of TsDPEN reduces monocyclic imines in up to 60% ee, whilst the N'-Me derivative of TsDPEN forms a more active catalyst than the non-alkylated analogue and reduces ketones in up to 97% ee. (C) 2010 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Hydrogenation, Ketones, Imines, Amines -- Synthesis, Ruthenium, Catalysis
Journal or Publication Title: Tetrahedron: Asymmetry
Publisher: Pergamon
ISSN: 0957-4166
Official Date: 27 September 2010
Dates:
DateEvent
27 September 2010Published
Volume: Vol.21
Number: No.18
Number of Pages: 7
Page Range: pp. 2258-2264
DOI: 10.1016/j.tetasy.2010.07.013
Status: Peer Reviewed
Publication Status: Published
Funder: Engineering and Physical Sciences Research Council (EPSRC)
Grant number: EP/F019424/1 (EPSRC)

Data sourced from Thomson Reuters' Web of Knowledge

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