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C60H2: recovery and decline - an investigation by MALDI mass spectrometry
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Nye, Leanne C., Tzirakis, Manolis D., Orfanopoulos, Michael and Drewello, Thomas. (2010) C60H2: recovery and decline - an investigation by MALDI mass spectrometry. Chemical Physics Letters, Vol.499 (No.4-6). pp. 209-212. ISSN 0009-2614
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Official URL: http://dx.doi.org/10.1016/j.cplett.2010.09.056
Abstract
The smallest hydro-[60]fullerene, C60H2, has been studied by matrix-assisted laser desorption/ionisation (MALDI) mass spectrometry. The ionisation of C60H2 was accomplished for the first time free of unwanted dissociations in electron transfer reactions with cations derived from the DCTB matrix. The findings pave the way to the use of MALDI for the quantitation of lower hydrofullerenes or investigations into the release of hydrogen. Direct LDI and negative-ion MALDI are less suited for a meaningful analysis. However, negative-ion MALDI reveals that C60H2 degrades through oxidation. (C) 2010 Elsevier B.V. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
| Divisions: | Faculty of Science > Chemistry |
| Journal or Publication Title: | Chemical Physics Letters |
| Publisher: | Elsevier BV |
| ISSN: | 0009-2614 |
| Date: | 29 October 2010 |
| Volume: | Vol.499 |
| Number: | No.4-6 |
| Number of Pages: | 4 |
| Page Range: | pp. 209-212 |
| Identification Number: | 10.1016/j.cplett.2010.09.056 |
| Status: | Peer Reviewed |
| Publication Status: | Published |
| Access rights to Published version: | Restricted or Subscription Access |
| URI: | http://wrap.warwick.ac.uk/id/eprint/4990 |
Data sourced from Thomson Reuters' Web of Knowledge
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