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Yb3O(OH)(6)Cl center dot 2H(2)O : an anion-exchangeable hydroxide with a cationic inorganic framework structure

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Goulding, Helen V., Hulse, Sarah E., Clegg, William, Harrington, Ross W., Playford, Helen Y., Walton, Richard I. and Fogg, Andrew M.. (2010) Yb3O(OH)(6)Cl center dot 2H(2)O : an anion-exchangeable hydroxide with a cationic inorganic framework structure. Journal of the American Chemical Society, Vol.132 (No.39). pp. 13618-13620. ISSN 0002-7863

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Official URL: http://dx.doi.org/10.1021/ja104636x

Abstract

The first anion-exchangeable framework hydroxide, Yb3O(OH)(6)Cl center dot 2H(2)O, has been synthesized hydrothermally. This material has a three-dimensional cationic ytterbium oxyhydroxide framework with one-dimensional channels running through the structure in which the chloride anions and water molecules are located. The framework is thermally stable below 200 degrees C and can be reversibly dehydrated and rehydrated with no loss of crystallinity. Additionally, it is able to undergo anion-exchange reactions with small ions such as carbonate, oxalate, and succinate with retention of the framework structure.

Item Type:

Journal Article

Subjects:

Q Science > QD Chemistry

Divisions:

Faculty of Science > Chemistry

Library of Congress Subject Headings (LCSH):

Layered double hydroxides, Anions, Crystals -- Structure, Inorganic ion exchange materials

Journal or Publication Title:

Journal of the American Chemical Society

Publisher:

American Chemical Society

ISSN:

0002-7863

Official Date:

6 October 2010

Dates:

Date	Event
6 October 2010	Published

Volume:

Vol.132

Number:

No.39

Number of Pages:

Page Range:

pp. 13618-13620

Identification Number:

10.1021/ja104636x

Status:

Peer Reviewed

Publication Status:

Published

Access rights to Published version:

Restricted or Subscription Access

Funder:

Royal Society (Great Britain), Engineering and Physical Sciences Research Council (EPSRC), Advantage West Midlands (AWM), European Regional Development Fund (ERDF)

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