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Yb3O(OH)(6)Cl center dot 2H(2)O : an anion-exchangeable hydroxide with a cationic inorganic framework structure

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Goulding, Helen V., Hulse, Sarah E., Clegg, William, 1949-, Harrington, Ross W., Playford, Helen Y., Walton, Richard I. and Fogg, Andrew M.. (2010) Yb3O(OH)(6)Cl center dot 2H(2)O : an anion-exchangeable hydroxide with a cationic inorganic framework structure. Journal of the American Chemical Society, Vol.132 (No.39). pp. 13618-13620. ISSN 0002-7863

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Abstract

The first anion-exchangeable framework hydroxide, Yb3O(OH)(6)Cl center dot 2H(2)O, has been synthesized hydrothermally. This material has a three-dimensional cationic ytterbium oxyhydroxide framework with one-dimensional channels running through the structure in which the chloride anions and water molecules are located. The framework is thermally stable below 200 degrees C and can be reversibly dehydrated and rehydrated with no loss of crystallinity. Additionally, it is able to undergo anion-exchange reactions with small ions such as carbonate, oxalate, and succinate with retention of the framework structure.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Layered double hydroxides, Anions, Crystals -- Structure, Inorganic ion exchange materials
Journal or Publication Title: Journal of the American Chemical Society
Publisher: American Chemical Society
ISSN: 0002-7863
Official Date: 6 October 2010
Volume: Vol.132
Number: No.39
Number of Pages: 3
Page Range: pp. 13618-13620
Identification Number: 10.1021/ja104636x
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Royal Society (Great Britain), Engineering and Physical Sciences Research Council (EPSRC), Advantage West Midlands (AWM), European Regional Development Fund (ERDF)
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URI: http://wrap.warwick.ac.uk/id/eprint/5019

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