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Yb3O(OH)(6)Cl center dot 2H(2)O : an anion-exchangeable hydroxide with a cationic inorganic framework structure
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Goulding, Helen V., Hulse, Sarah E., Clegg, William, Harrington, Ross W., Playford, Helen Y., Walton, Richard I. and Fogg, Andrew M. (2010) Yb3O(OH)(6)Cl center dot 2H(2)O : an anion-exchangeable hydroxide with a cationic inorganic framework structure. Journal of the American Chemical Society, Vol.132 (No.39). pp. 13618-13620. doi:10.1021/ja104636x
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Official URL: http://dx.doi.org/10.1021/ja104636x
Abstract
The first anion-exchangeable framework hydroxide, Yb3O(OH)(6)Cl center dot 2H(2)O, has been synthesized hydrothermally. This material has a three-dimensional cationic ytterbium oxyhydroxide framework with one-dimensional channels running through the structure in which the chloride anions and water molecules are located. The framework is thermally stable below 200 degrees C and can be reversibly dehydrated and rehydrated with no loss of crystallinity. Additionally, it is able to undergo anion-exchange reactions with small ions such as carbonate, oxalate, and succinate with retention of the framework structure.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Layered double hydroxides, Anions, Crystals -- Structure, Inorganic ion exchange materials | ||||
| Journal or Publication Title: | Journal of the American Chemical Society | ||||
| Publisher: | American Chemical Society | ||||
| ISSN: | 0002-7863 | ||||
| Official Date: | 6 October 2010 | ||||
| Dates: |
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| Volume: | Vol.132 | ||||
| Number: | No.39 | ||||
| Number of Pages: | 3 | ||||
| Page Range: | pp. 13618-13620 | ||||
| DOI: | 10.1021/ja104636x | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Royal Society (Great Britain), Engineering and Physical Sciences Research Council (EPSRC), Advantage West Midlands (AWM), European Regional Development Fund (ERDF) |
Data sourced from Thomson Reuters' Web of Knowledge
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