Jenkins, H. Donald Brooke and Glasser, Leslie. (2010) Thermodynamic difference rules: a prescription for their application and usage to approximate thermodynamic data. Journal of Chemical and Engineering Data, Vol.55 (No.10). pp. 4231-4238. ISSN 0021-9568

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Abstract

Thermodynamic data are required for an understanding of the behavior of materials hut are often lacking (or even unreliable) for a variety of reasons such as synthetic problems, purity issues, failure to correctly identify hydrolysis products, instability of the material. etc. Thus, it is necessary to develop procedures for the estimation of that data. The Thermodynamic Difference Rules (TDR) are additive approximations by which the properties of materials are estimated by reference to those of related materials. These rules appear in the form of the reliable Hydrate Difference Rule (HDR), based on the well-established properties of the large number of known hydrates, and the somewhat less certain Solvate Difference Rule (SDR). These rules are briefly surveyed and their application carefully delineated by a scheme and demonstrated by a number of calculated examples.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry T Technology > TP Chemical technology
Divisions:	Faculty of Science > Chemistry
Journal or Publication Title:	Journal of Chemical and Engineering Data
Publisher:	American Chemical Society
ISSN:	0021-9568
Date:	October 2010
Volume:	Vol.55
Number:	No.10
Number of Pages:	8
Page Range:	pp. 4231-4238
Identification Number:	10.1021/je100383t
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
URI:	http://wrap.warwick.ac.uk/id/eprint/5022

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