Jenkins, H. Donald Brooke, Glasser, Leslie and Liebman, Joel F.. (2010) The thermodynamic Hydrate Difference Rule (HDR) applied to salts of carbon-containing oxyacid salts and their hydrates: materials at the inorganic-organic interface. Journal of Chemical and Engineering Data, Vol.55 (No.10). pp. 4369-4371. ISSN 0021-9568

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Abstract

The thermodynamic hydrate difference rule (HDR) has previously been explored largely within the compass of inorganic solids. In this paper we extend its range by studying its application to carbon-containing oxyacid salts, which may be regarded as borderline hydrate-forming inorganic or organic material. We study in detail standard thermodynamic data as it appears in the National Bureau of Standards (NBS) tabulation for formate, carbonate, acetate. glycolate, and oxalate salt hydrates, finding the HDR to apply equally as well to these materials as it does to salts with solely inorganic parents. We use the resulting constants to predict thermodynamic quantities for some parent salts.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry T Technology > TP Chemical technology
Divisions:	Faculty of Science > Chemistry
Journal or Publication Title:	Journal of Chemical and Engineering Data
Publisher:	American Chemical Society
ISSN:	0021-9568
Date:	October 2010
Volume:	Vol.55
Number:	No.10
Number of Pages:	3
Page Range:	pp. 4369-4371
Identification Number:	10.1021/je100543e
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
URI:	http://wrap.warwick.ac.uk/id/eprint/5023

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