Patten, Hollie V., Meadows, Katherine E., Hutton, Laura A., Iacobini, James G., Battistel, Dario, McKelvey, Kim M. (Kim Martin), Colburn, Alexander W., Newton, Mark E., Macpherson, Julie V. and Unwin, Patrick R.. (2012) Electrochemical mapping reveals direct correlation between heterogeneous electron-transfer kinetics and local density of states in diamond electrodes. Angewandte Chemie International Edition, Volume 51 (Number 28). pp. 7002-7006. ISSN 1433-7851

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Abstract

Conducting carbon materials: A multi-microscopy approach shows that local heterogeneous electron-transfer rates at conducting diamond electrodes correlate with the local density of electronic states. This model of electroactivity is of considerable value for the rational design of conducting diamond electrochemical technologies, and also provides key general insights on electrode structure controls in electrochemical kinetics

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry Faculty of Science > Molecular Organisation and Assembly in Cells (MOAC) Faculty of Science > Physics
Library of Congress Subject Headings (LCSH):	Electrochemistry, High resolution electron microscopy, Chemical kinetics, Charge exchange, Electrodes
Journal or Publication Title:	Angewandte Chemie International Edition
Publisher:	Wiley - V C H Verlag GmbH & Co. KGaA
ISSN:	1433-7851
Date:	July 2012
Volume:	Volume 51
Number:	Number 28
Page Range:	pp. 7002-7006
Identification Number:	10.1002/anie.201203057
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Engineering and Physical Sciences Research Council (EPSRC) , University of Warwick. Molecular Organisation and Assembly in Cells, Element Six, European Research Council (ERC), Advantage West Midlands (AWM), European Regional Development Fund (ERDF)
Grant number:	ERC-2009-AdG 247143-QUANTIF
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URI:	http://wrap.warwick.ac.uk/id/eprint/50926

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