A lithium–organic framework with coordinatively unsaturated metal sites that reversibly binds water
Osta, Racha El, Frigoli, Michel, Marrot, Jérôme, Guillou, Nathalie, Chevreau, Hubert, Walton, Richard I. and Millange, Franck. (2012) A lithium–organic framework with coordinatively unsaturated metal sites that reversibly binds water. Chemical Communications, Vol.48 (No.86). pp. 10639-10641. ISSN 1359-7345Full text not available from this repository.
Official URL: http://dx.doi.org/10.1039/C2CC35861A
The synthesis and characterisation of a three-dimensional lithium–organic framework MIL-145 is described, which upon thermal treatment yields a second open framework, MIL-146, that contains four and three-coordinate lithium centres: the coordinatively unsaturated trigonal planar lithium centres are able to reversibly bind water with crystallinity maintained, while the dehydrated phase shows preferential adsorption of CO2 over N2.
|Item Type:||Journal Article|
|Divisions:||Faculty of Science > Chemistry|
|Journal or Publication Title:||Chemical Communications|
|Publisher:||Royal Society of Chemistry|
|Page Range:||pp. 10639-10641|
|Access rights to Published version:||Restricted or Subscription Access|
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