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A lithium–organic framework with coordinatively unsaturated metal sites that reversibly binds water
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Osta, Racha El, Frigoli, Michel, Marrot, Jérôme, Guillou, Nathalie, Chevreau, Hubert, Walton, Richard I. and Millange, Franck. (2012) A lithium–organic framework with coordinatively unsaturated metal sites that reversibly binds water. Chemical Communications, Vol.48 (No.86). pp. 10639-10641. ISSN 1359-7345
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Official URL: http://dx.doi.org/10.1039/C2CC35861A
Abstract
The synthesis and characterisation of a three-dimensional lithium–organic framework MIL-145 is described, which upon thermal treatment yields a second open framework, MIL-146, that contains four and three-coordinate lithium centres: the coordinatively unsaturated trigonal planar lithium centres are able to reversibly bind water with crystallinity maintained, while the dehydrated phase shows preferential adsorption of CO2 over N2.
| Item Type: | Journal Article |
|---|---|
| Divisions: | Faculty of Science > Chemistry |
| Journal or Publication Title: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| Date: | 2012 |
| Volume: | Vol.48 |
| Number: | No.86 |
| Page Range: | pp. 10639-10641 |
| Identification Number: | 10.1039/C2CC35861A |
| Status: | Peer Reviewed |
| Publication Status: | Published |
| Access rights to Published version: | Restricted or Subscription Access |
| URI: | http://wrap.warwick.ac.uk/id/eprint/52054 |
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