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Relieving steric strain at octahedral platinum(IV) : isomerization and reductive coupling of alkyl and aryl chlorides
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Crosby, Sarah H., Clarkson, Guy J. and Rourke, Jonathan (2012) Relieving steric strain at octahedral platinum(IV) : isomerization and reductive coupling of alkyl and aryl chlorides. Organometallics, Vol.31 (No.20). pp. 7256-7263. doi:10.1021/om3008019 ISSN 0276-7333.
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Official URL: http://dx.doi.org/10.1021/om3008019
Abstract
Oxidation of monocyclometalated platinum(II) complexes results in octahedral platinum(IV) complexes. Depending on the substitution, two different reactions occur: either a simple isomerization, resulting in the exchange of ligand positions, or a reductive coupling of aryl chloride. With a doubly cyclometalated complex, stability of the oxidized form is dependent on isomeric form: whereas the trans isomer is robust, being manipulable in air at room temperature, the cis isomer decomposes at -20 °C and above. Reductive coupling at this cis isomer is 100% selective for alkyl chloride over aryl chloride and is suggested to be a concerted process. © 2012 American Chemical Society.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Journal or Publication Title: | Organometallics | ||||
| Publisher: | American Chemical Society | ||||
| ISSN: | 0276-7333 | ||||
| Official Date: | 22 October 2012 | ||||
| Dates: |
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| Volume: | Vol.31 | ||||
| Number: | No.20 | ||||
| Page Range: | pp. 7256-7263 | ||||
| DOI: | 10.1021/om3008019 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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