Garino, Claudio, Gallo, Erik, Smolentsev, Nikolay, Glatzel, Pieter, Gobetto, Roberto, Lamberti, Carlo, Sadler, P. J. and Salassa, Luca. (2012) Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex. Physical Chemistry Chemical Physics, Vol.14 (No.44). pp. 15278-15281. ISSN 1463-9076

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Abstract

Resonant X-ray Emission Spectroscopy (RXES) is used to characterize the ligand field states of the prototypic self-assembled square-planar complex, [Pt(tpy)Cl]Cl (tpy=2,2′:6′,2′′-terpyridine), and determine the effect of weak metal-metal and π-π interactions on their energy. © 2012 the Owner Societies.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Self-assembly (Chemistry), X-ray spectroscopy, Platinum, Transition metal complexes, Supramolecular chemistry
Journal or Publication Title:	Physical Chemistry Chemical Physics
Publisher:	Royal Society of Chemistry
ISSN:	1463-9076
Date:	28 November 2012
Volume:	Vol.14
Number:	No.44
Page Range:	pp. 15278-15281
Identification Number:	10.1039/c2cp42451g
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	European Synchrotron Radiation Facility (ESRF), European Research Council (ERC), Spain. Ministerio de Ciencia e Innovación (MICINN)
Grant number:	CH3108 (ESRF), 247450 (ERC), RYC-2011-07787 (MICINN)
References:	1. V. W.-W. Yam and K. M.-C. Wong, Chem. Commun., 2011, 47, 11579-11592. 2. A. J. Goshe, I. M. Steele and B. Bosnich, J. Am. Chem. Soc., 2003, 125, 444-451. 3. D. R. McMillin and J. J. Moore, Coord. Chem. Rev., 2002, 229, 113-121. 4. V. Adamovich, J. Brooks, A. Tamayo, A. M. Alexander, P. I. Djurovich, B. W. D'Andrade, C. Adachi, S. R. Forrest and M. E. Thompson, New J. Chem., 2002, 26, 1171-1178. 5. V. W. W. Yam, K. M. C. Wong and N. Y. Zhu, Angew. Chem. Int. Ed., 2003, 42, 1400-1403. 6. C. Yu, K. H.-Y. Chan, K. M.-C. Wong and V. W.-W. Yam, Chem. Commun., 2009, 3756-3758. 7. A. M. Krause-Heuer, N. J. Wheate, W. S. Price and J. Aldrich-Wright, Chem. Commun., 2009, 1210-1212. 8. G. Arena, L. M. Scolaro, R. F. Pasternack and R. Romeo, Inorg. Chem., 1995, 34, 2994-3002. 9. J. A. Bailey, M. G. Hill, R. E. Marsh, V. M. Miskowski, W. P. Schaefer and H. B. Gray, Inorg. Chem., 1995, 34, 4591-4599. 10. H. K. Yip, L. K. Cheng, K. K. Cheung and C. M. Che, J. Chem. Soc., Dalton Trans., 1993, 2933-2938. 11. U. Bergmann and P. Glatzel, Photosynth. Res., 2009, 102, 255-266. 12. P. Glatzel and U. Bergmann, Coord. Chem. Rev., 2005, 249, 65-95. 13. G. Lowe, A. S. Droz, T. Vilaivan, G. W. Weaver, J. J. Park, J. M. Pratt, L. Tweedale and L. R. Kelland, J. Med. Chem., 1999, 42, 3167-3174. 14. S. J. Lippard, Acc. Chem. Res., 1978, 11, 211-217. 15. E. M. A. Ratilla, H. M. Brothers and N. M. Kostic, J. Am. Chem. Soc., 1987, 109, 4592-4599. 16. C. Gauthier, V. A. Sole, R. Signorato, J. Goulon and E. Moguiline, J. Synchrot. Radiat., 1999, 6, 164-166. 17. P. Glatzel, J. Singh, K. O. Kvashnina and J. A. van Bokhoven, J. Am. Chem. Soc., 2010, 132, 2555-2557. 18. N. Smolentsev, M. Sikora, A. V. Soldatov, K. O. Kvashnina and P. Glatzel, Phys. Rev. B, 2011, 84. 19. A. Kotani and S. Shin, Rev. Mod. Phys., 2001, 73, 203-246. 20. F. Gel'mukhanov and H. Agren, Phys. Rep.-Rev. Sec. Phys. Lett., 1999, 312, 87-330. 21. J. Jimenez-Mier, J. van Ek, D. L. Ederer, T. A. Callcott, J. J. Jia, J. Carlisle, L. Terminello, A. Asfaw and R. C. Perera, Phys. Rev. B, 1999, 59, 2649-2658. 22. P. Blaha, K. Schwarz, G. K. H. Madsen, D. Kvasnicka and J. Luitz, WIEN2k: An Augmented Plane Wave + Local Orbitals Program for Calculating Crystal Properties, (2001) Karlheinz Schwarz Technische Universität, Wien, Austria. 23. K. Schwarz, P. Blaha and S. B. Trickey, Mol. Phys., 2010, 108, 3147-3166. 24. R. G. Dickinson, J. Am. Chem. Soc., 1922, 44, 2404-2411. 25. P. Glatzel, U. Bergmann, J. Yano, H. Visser, J. H. Robblee, W. W. Gu, F. M. F. de Groot, G. Christou, V. L. Pecoraro, S. P. Cramer and V. K. Yachandra, J. Am. Chem. Soc., 2004, 126, 9946-9959. 26. J. Tao, J. P. Perdew, V. N. Staroverov and G. E. Scuseria, Phys. Rev. Lett., 2003, 91, 146401. 27. P. Fuentealba, H. Preuss, H. Stoll and L. Von Szentpály, Chem. Phys. Lett., 1982, 89, 418-422. 28. R. Ditchfield, W. J. Hehre and J. A. Pople, J. Chem. Phys., 1971, 54, 724-728. 29. K. Krogmann, Angew. Chem. Int. Ed., 1969, 8, 35-42. 30. A. Dedieu, Chem. Rev., 2000, 100, 543-600.
URI:	http://wrap.warwick.ac.uk/id/eprint/52150

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