The Library
Organocatalytic synthesis and post-polymerization functionalization of propargyl-functional poly(carbonate)s
Tools
Tools
Tools
Tempelaar, Sarah, Barker, Ian A., Truong, V, Hall, Daniel J., Mespouille, Laetitia, Dubois, Philippe and Dove, Andrew P. (2013) Organocatalytic synthesis and post-polymerization functionalization of propargyl-functional poly(carbonate)s. Polymer Chemistry, Vol.4 (No.1). pp. 174-183. doi:10.1039/c2py20718d
Research output not available from this repository, contact author.
Official URL: http://dx.doi.org/10.1039/C2PY20718D
Abstract
The synthesis of well-defined propargyl-functional poly(carbonate)s was achieved via the organocatalytic ring-opening polymerization of 5-methyl-5-propargyloxycarbonyl-1,3-dioxan-2-one (MPC) using the dual catalyst system of 1-(3,5-bis(trifluoromethyl)phenyl)-3-cyclohexylthiourea (TU) and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU). The resulting homopolymers showed low dispersities and high end-group fidelity, with the versatility of the system being demonstrated by the synthesis of telechelic copolymers and block copolymers. The synthesized homopolymers with varying degree of polymerization were functionalized with a range of azides via copper-catalyzed Huisgen-1,3-dipolar addition or thiols via radical thiylation, to produce functional aliphatic poly(carbonate)s from a single polymeric scaffold
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science > Chemistry | ||||
| Journal or Publication Title: | Polymer Chemistry | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1759-9954 | ||||
| Official Date: | 2013 | ||||
| Dates: |
|
||||
| Volume: | Vol.4 | ||||
| Number: | No.1 | ||||
| Page Range: | pp. 174-183 | ||||
| DOI: | 10.1039/c2py20718d | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published |
Request changes or add full text files to a record
Repository staff actions (login required)
 |
View Item |
