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Asymmetric transfer hydrogenation of quinolines using tethered Ru(II) catalysts
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Parekh, Vimal, Ramsden, James A. and Wills, Martin (2010) Asymmetric transfer hydrogenation of quinolines using tethered Ru(II) catalysts. Tetrahedron: Asymmetry, Vol.21 (No.11-12). pp. 1549-1556. doi:10.1016/j.tetasy.2010.03.053
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Official URL: http://dx.doi.org/10.1016/j.tetasy.2010.03.053
Abstract
The first report of an asymmetric transfer hydrogenation, in formic acid/triethylamine, of quinolines is described. Using a Ru(II) catalyst containing a 4-carbon tether, products of up to 73% ee were formed, whilst a Rh(III)-tethered catalyst gave products of up to 94% ee. (C) 2010 Elsevier Ltd. All rights reserved.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Hydrogenation, Ruthenium, Quinoline, Catalysis | ||||
| Journal or Publication Title: | Tetrahedron: Asymmetry | ||||
| Publisher: | Pergamon | ||||
| ISSN: | 0957-4166 | ||||
| Official Date: | 23 June 2010 | ||||
| Dates: |
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| Volume: | Vol.21 | ||||
| Number: | No.11-12 | ||||
| Number of Pages: | 8 | ||||
| Page Range: | pp. 1549-1556 | ||||
| DOI: | 10.1016/j.tetasy.2010.03.053 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Engineering and Physical Sciences Research Council (EPSRC), Dr. Reddy's Laboratories |
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