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Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation
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Barker, Ian A. and Dove, Andrew P. (2013) Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation. Chemical Communications, Vol.49 (No.12). pp. 1205-1207. doi:10.1039/c2cc38114a ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/C2CC38114A
Abstract
Triarylsulfonium hexafluorophosphate salts were shown to be effective catalysts for the ring-opening polymerisation of various cyclic monomers under UV irradiation. A dual basic/acidic catalytic system demonstrated the potential for UV-triggered formation of poly(δ-valerolactone)-b-poly(L-lactide)-b-poly(δ-valerolactone) in a ‘one-pot’ reaction.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Journal or Publication Title: | Chemical Communications | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1359-7345 | ||||
| Official Date: | 2013 | ||||
| Dates: |
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| Volume: | Vol.49 | ||||
| Number: | No.12 | ||||
| Page Range: | pp. 1205-1207 | ||||
| DOI: | 10.1039/c2cc38114a | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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