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Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation

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Barker, Ian A. and Dove, Andrew P. (2013) Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation. Chemical Communications, Vol.49 (No.12). pp. 1205-1207. doi:10.1039/c2cc38114a ISSN 1359-7345.

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Official URL: http://dx.doi.org/10.1039/C2CC38114A

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Abstract

Triarylsulfonium hexafluorophosphate salts were shown to be effective catalysts for the ring-opening polymerisation of various cyclic monomers under UV irradiation. A dual basic/acidic catalytic system demonstrated the potential for UV-triggered formation of poly(δ-valerolactone)-b-poly(L-lactide)-b-poly(δ-valerolactone) in a ‘one-pot’ reaction.

Item Type: Journal Article
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Journal or Publication Title: Chemical Communications
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Official Date: 2013
Dates:
DateEvent
2013Published
Volume: Vol.49
Number: No.12
Page Range: pp. 1205-1207
DOI: 10.1039/c2cc38114a
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access

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