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Orthogonal modification of norbornene-functional degradable polymers
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Williams, Rebecca J., Barker, Ian A., O’Reilly, Rachel K. and Dove, Andrew P. (2012) Orthogonal modification of norbornene-functional degradable polymers. ACS Macro Letters, Vol.1 (No.11). pp. 1285-1290. doi:10.1021/mz300496q
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Official URL: http://dx.doi.org/10.1021/mz300496q
Abstract
Well-defined norbornene-functional poly(carbonate)s were prepared by ring-opening polymerization and utilized as multireactive polymeric scaffolds in a range of postpolymerization modifications. The norbornene-functional handles were shown to undergo facile reaction with azides via a 1,3-dipolar cycloaddition, tetrazines in the inverse electron demand Diels–Alder reaction and thiols via radical thiol-ene coupling. Furthermore, the above-mentioned chemistries were demonstrated in a sequential one-pot, three-step modification reaction illustrating the potential of these polymers as scaffolds to access multifunctionalized materials in an undemanding manner.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Journal or Publication Title: | ACS Macro Letters | ||||
| Publisher: | American Chemical Society | ||||
| ISSN: | 2161-1653 | ||||
| Official Date: | 2012 | ||||
| Dates: |
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| Volume: | Vol.1 | ||||
| Number: | No.11 | ||||
| Page Range: | pp. 1285-1290 | ||||
| DOI: | 10.1021/mz300496q | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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