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A novel flow battery : a lead acid battery based on an electrolyte with soluble lead(II). Part IX : electrode and electrolyte conditioning with hydrogen peroxide
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Collins, John, Li, Xiaohong, Pletcher, Derek, Tangirala, Ravichandra, Stratton-Campbell, Duncan, Walsh, Frank C. and Zhang, Caiping (2010) A novel flow battery : a lead acid battery based on an electrolyte with soluble lead(II). Part IX : electrode and electrolyte conditioning with hydrogen peroxide. Journal of Power Sources, Vol.195 (No.9). pp. 2975-2978. doi:10.1016/j.jpowsour.2009.10.109
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Official URL: http://dx.doi.org/10.1016/j.jpowsour.2009.10.109
Abstract
Extended cycling of a soluble lead acid battery can lead to problems due to an imbalance in the coulombic efficiency leading to deposits of Pb and PbO2 on the electrodes. Periodic addition of hydrogen peroxide to the electrolyte of the soluble lead acid flow battery largely overcomes several operational problems seen during extended cycling, using a 10 cm × 10 cm parallel plate flow cell. It is shown that this treatment greatly extends the number of cycles that can be achieved with a reasonable energy-, voltage-, and charge efficiency of 54–66%, 71%, and 77–91%.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science > WMG (Formerly the Warwick Manufacturing Group) | ||||
| Journal or Publication Title: | Journal of Power Sources | ||||
| Publisher: | Elsevier S.A. | ||||
| ISSN: | 0378-7753 | ||||
| Official Date: | 1 May 2010 | ||||
| Dates: |
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| Volume: | Vol.195 | ||||
| Number: | No.9 | ||||
| Page Range: | pp. 2975-2978 | ||||
| DOI: | 10.1016/j.jpowsour.2009.10.109 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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