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Platinum(II) n-heterocyclic carbene complexes : coordination and cyclometallation
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Petretto, Giacomo L., Wang, Miao, Zucca, Antonio and Rourke, Jonathan (2010) Platinum(II) n-heterocyclic carbene complexes : coordination and cyclometallation. Dalton Transactions, Vol.39 (No.33). pp. 7822-7825. doi:10.1039/c0dt00435a ISSN 1477-9226.
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Official URL: http://dx.doi.org/10.1039/c0dt00435a
Abstract
Four different NHC ligands have been coordinated to Pt(II) centres; for the first time cyclometallation of the NHC ligand was observed, but only when the platinum centre had a DMSO and two methyl co-ligands. Cyclometallation resulted in the exclusive formation of five-membered rings, and the absence of any double cyclometallation reactions with appropriate ligands rules out the possibility of an oxidative addition type mechanism for the cyclometallation reaction.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Platinum, Ligands | ||||
Journal or Publication Title: | Dalton Transactions | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1477-9226 | ||||
Official Date: | 23 July 2010 | ||||
Dates: |
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Volume: | Vol.39 | ||||
Number: | No.33 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 7822-7825 | ||||
DOI: | 10.1039/c0dt00435a | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Date of first compliant deposit: | 3 December 2015 | ||||
Date of first compliant Open Access: | 3 December 2015 |
Data sourced from Thomson Reuters' Web of Knowledge
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