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The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates

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Anastasaki, Athina, Waldron, Christopher, Wilson, Paul, McHale, Ronan and Haddleton, David M. (2013) The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates. Polymer Chemistry, Volume 4 (Number 9). pp. 2672-2675. doi:10.1039/c3py00270e

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Official URL: http://dx.doi.org/10.1039/C3PY00270E

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Abstract

Ligand mediated termination events occur during the homo-polymerisation of methyl (MA) and butyl (BA) acrylate under SET-LRP (Cu(0) mediated) conditions. Careful optimization of [initiator]/[ligand] (Me6Tren) ratios is required to reduce termination in order to achieve optimum polymerisation.

Item Type: Journal Article
Divisions: Faculty of Science > Chemistry
Journal or Publication Title: Polymer Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1759-9954
Official Date: March 2013
Dates:
DateEvent
March 2013Published
Volume: Volume 4
Number: Number 9
Page Range: pp. 2672-2675
DOI: 10.1039/c3py00270e
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access

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