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Heterobimetallic rollover derivatives
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Petretto, Giacomo L., Rourke, Jonathan, Maidich, Luca, Stoccoro, Sergio, Cinellu, Maria Agostina, Minghetti, Giovanni, Clarkson, Guy J. and Zucca, Antonio (2012) Heterobimetallic rollover derivatives. Organometallics, Volume 31 (Number 8). pp. 2971-2977. doi:10.1021/om200660a ISSN 0276-7333.
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Official URL: http://dx.doi.org/10.1021/om200660a
Abstract
Heterobimetallic complexes with metal centers connected by a small delocalized ligand constitute an interesting class of compounds. Here we report that starting from the mononuclear platinum(II) rollover complexes [Pt(bipy-H)(L)Cl] (bipy-H = 2,2′-bipyridine C(3′)-N cyclometalated, L= DMSO, PPh3) a second rollover cyclometalation may produce a series of Pt(II)/Pd(II) heterobimetallic complexes where the two metals are linked by the planar, highly delocalized, doubly deprotonated 2,2′-bipyridine.
Item Type: | Journal Article | ||||
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Journal or Publication Title: | Organometallics | ||||
Publisher: | American Chemical Society | ||||
ISSN: | 0276-7333 | ||||
Official Date: | 23 April 2012 | ||||
Dates: |
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Volume: | Volume 31 | ||||
Number: | Number 8 | ||||
Page Range: | pp. 2971-2977 | ||||
DOI: | 10.1021/om200660a | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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