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A sweet origin for the key congocidine precursor 4-acetamidopyrrole-2-carboxylate
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Lautru, Sylvie, Song, Lijiang, Demange, Luc, Lombès, Thomas, Galons, Hervé, Challis, Gregory L. and Pernodet, Jean-Luc (2012) A sweet origin for the key congocidine precursor 4-acetamidopyrrole-2-carboxylate. Angewandte Chemie International Edition, Volume 51 (Number 30). pp. 7454-7458. doi:10.1002/anie.201201445 ISSN 1433-7851.
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Official URL: http://dx.doi.org/10.1002/anie.201201445
Abstract
Feeding (Streptomyces) frenzy: Natural products belonging to the pyrrolamide family are defined by their pyrrole-2-carboxamide moiety. 4-acetamidopyrrole-2-carboxylate is identified as the key pyrrolamide congocidine precursor (see scheme) through feeding studies using Streptomyces ambofaciens. The biosynthetic pathway of congocidine starts with the carbohydrate N-acetylglucosamine and involves carbohydrate-processing enzymes.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Journal or Publication Title: | Angewandte Chemie International Edition | ||||
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
| ISSN: | 1433-7851 | ||||
| Official Date: | 23 July 2012 | ||||
| Dates: |
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| Volume: | Volume 51 | ||||
| Number: | Number 30 | ||||
| Page Range: | pp. 7454-7458 | ||||
| DOI: | 10.1002/anie.201201445 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published |
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