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Mutual binding of polymer end-groups by complementary π–π-stacking : a molecular “Roman Handshake”
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Greenland, Barnaby W., Bird, Matthew B., Burattini, Stefano, Cramer, Rainer, O'Reilly, Rachel K., Patterson, Joseph P., Hayes, Wayne, Cardin, Christine J. and Colquhoun, Howard M. (2013) Mutual binding of polymer end-groups by complementary π–π-stacking : a molecular “Roman Handshake”. Chemical Communications, Volume 49 (Number 5). pp. 454-546. doi:10.1039/c2cc35965k
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Official URL: http://dx.doi.org/10.1039/C2CC35965K
Abstract
Self-complementary tweezer-molecules based on a naphthalenediimide core self-assemble into supramolecular dimers through mutual π–π-stacking and hydrogen bonding. The resulting motif is extremely stable in solution (Ka = 105 M−1), and its attachment to one terminal position of a poly(ethylene glycol) chain leads to a doubling of the polymer's apparent molecular weight.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science > Chemistry | ||||
| Journal or Publication Title: | Chemical Communications | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1359-7345 | ||||
| Official Date: | 2013 | ||||
| Dates: |
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| Volume: | Volume 49 | ||||
| Number: | Number 5 | ||||
| Page Range: | pp. 454-546 | ||||
| DOI: | 10.1039/c2cc35965k | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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