Skey, Jared, Willcock, Helen, Lammens, Mieke, Du Prez, Filip E. and O'Reilly, Rachel K.. (2010) Synthesis and self-assembly of amphiphilic chiral poly(amino acid) star polymers. Macromolecules, Vol.43 (No.14). pp. 5949-5955. ISSN 0024-9297

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Abstract

Reversible addition-fragmentation chain transfer (RAFT) polymerization techniques were utilized to polymerize N-acryloyl-L-phenylalanine methyl ester (L-Phe-OMe) and tetrahydropyranyl acrylate to afford amphiphilic star polymers (with 4 and 6 arms) These copolymer stars have a chiral hydrophobic core domain and can undergo further solution self-assembly to form well-defined nanostructures, which have been characterized using DLS, TEM, and cryo-TEM analysis The characterization and properties of these novel chiral assemblies and their potential in racemic resolution are reported

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Biosynthesis, Polymers, Self-assembly (Chemistry), Polymerization, Block copolymers, Polystyrene, Micelles
Journal or Publication Title:	Macromolecules
Publisher:	American Chemical Society
ISSN:	0024-9297
Official Date:	27 July 2010
Dates:	Date Event 27 July 2010 Published
Volume:	Vol.43
Number:	No.14
Number of Pages:	7
Page Range:	pp. 5949-5955
Identification Number:	10.1021/ma101019g
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Royal Society (Great Britain), Agentschap voor Innovatie door Wetenschap en Technologie [Agency for Innovation by Science and Technology] (IWT), Leverhulme Trust (LT), University of Warwick, Engineering and Physical Sciences Research Council (EPSRC)
URI:	http://wrap.warwick.ac.uk/id/eprint/5501

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