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Dual-functional materials via CCTP and selective orthogonal thiol-Michael addition/epoxide ring opening reactions

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McEwan, Kayleigh A., Slavin, Stacy, Tunnah, Edward J. and Haddleton, David M. (2013) Dual-functional materials via CCTP and selective orthogonal thiol-Michael addition/epoxide ring opening reactions. Polymer Chemistry, Volume 4 (Number 8). pp. 2608-2614. doi:10.1039/c3py21104e ISSN 1759-9954.

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Official URL: http://dx.doi.org/10.1039/C3PY21104E

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Abstract

Poly(glycidyl methacrylate) (PGMA) has been synthesised by cobalt catalysed chain transfer polymerisation (CCTP) yielding, in one step, polymers with two points for post polymerisation functionalisation; the activated terminal vinyl bond and in chain epoxide groups. Epoxide ring-opening and a combination of thiol-Michael addition and epoxide ring-opening has been used for the post-functionalisation with amines and thiols to prepare a range of functional materials.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH): Polymers , Polymerization, Chemical reactions, Ring-opening polymerization, Epoxy compounds
Journal or Publication Title: Polymer Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1759-9954
Official Date: 2013
Dates:
DateEvent
2013Published
Volume: Volume 4
Number: Number 8
Page Range: pp. 2608-2614
DOI: 10.1039/c3py21104e
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Open Access (Creative Commons)
Date of first compliant deposit: 24 December 2015
Date of first compliant Open Access: 24 December 2015
Funder: Advantage West Midlands (AWM), European Regional Development Fund (ERDF), Engineering and Physical Sciences Research Council (EPSRC) , Agilent Technologies, Unilever (Firm)

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