McEwan, Kayleigh A., Slavin, Stacy, Tunnah, Edward J. and Haddleton, David M. (2013) Dual-functional materials via CCTP and selective orthogonal thiol-Michael addition/epoxide ring opening reactions. Polymer Chemistry, Volume 4 (Number 8). pp. 2608-2614. doi:10.1039/c3py21104e ISSN 1759-9954.

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Abstract

Poly(glycidyl methacrylate) (PGMA) has been synthesised by cobalt catalysed chain transfer polymerisation (CCTP) yielding, in one step, polymers with two points for post polymerisation functionalisation; the activated terminal vinyl bond and in chain epoxide groups. Epoxide ring-opening and a combination of thiol-Michael addition and epoxide ring-opening has been used for the post-functionalisation with amines and thiols to prepare a range of functional materials.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH):	Polymers , Polymerization, Chemical reactions, Ring-opening polymerization, Epoxy compounds
Journal or Publication Title:	Polymer Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1759-9954
Official Date:	2013
Dates:	Date Event 2013 Published
Volume:	Volume 4
Number:	Number 8
Page Range:	pp. 2608-2614
DOI:	10.1039/c3py21104e
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Open Access (Creative Commons)
Date of first compliant deposit:	24 December 2015
Date of first compliant Open Access:	24 December 2015
Funder:	Advantage West Midlands (AWM), European Regional Development Fund (ERDF), Engineering and Physical Sciences Research Council (EPSRC) , Agilent Technologies, Unilever (Firm)

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