The Library
Catalytic Y-tailed amphiphilic homopolymers – aqueous nanoreactors for high activity, low loading SCS pincer catalysts
Tools
Tools
Tools
Patterson, Joseph P., Cotanda, Pepa, Kelley, Elizabeth G., Moughton, Adam O., Lu, Annhelen, Epps, Thomas H. and O'Reilly, Rachel K. (2013) Catalytic Y-tailed amphiphilic homopolymers – aqueous nanoreactors for high activity, low loading SCS pincer catalysts. Polymer Chemistry, 4 (6). pp. 2033-2039. doi:10.1039/c3py21137a ISSN 1759-9954.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1039/C3PY21137A
Abstract
A new amphiphilic homopolymer bearing an SCS pincer palladium complex has been synthesized by reversible addition fragmentation chain transfer polymerization. The amphiphile has been shown to form spherical and worm-like micelles in water by cryogenic transmission electron microscopy and small angle neutron scattering. Segregation of reactive components within the palladium containing core results in increased catalytic activity of the pincer compound compared to small molecule analogues. This allows carbon–carbon bond forming reactions to be performed in water with reduced catalyst loadings and enhanced activity.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Journal or Publication Title: | Polymer Chemistry | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1759-9954 | ||||
| Official Date: | 28 January 2013 | ||||
| Dates: |
|
||||
| Volume: | 4 | ||||
| Number: | 6 | ||||
| Number of Pages: | 6 | ||||
| Page Range: | pp. 2033-2039 | ||||
| DOI: | 10.1039/c3py21137a | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published |
Request changes or add full text files to a record
Repository staff actions (login required)
 |
View Item |
