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Study of boron–nitrogen dative bonds using azetidine inversion dynamics
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Hoang, Cam Thuy, Prokes, Ivan, Clarkson, Guy J., Rowland, M. J., Tucker, James H. R., Shipman, Michael and Walsh, Tiffany R. (2013) Study of boron–nitrogen dative bonds using azetidine inversion dynamics. Chemical Communications, Volume 49 (Number 25). pp. 2509-2511. doi:10.1039/c3cc36159d
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Official URL: http://dx.doi.org/10.1039/c3cc36159d
Abstract
A method for probing the strength of B-N dative bonds is reported. The activation parameters for nitrogen inversion in a series of azetidines tethered to boronate esters have been quantified by VT-NMR and the measured barriers correlated with data obtained by 11B NMR, X-ray crystallography and MP2 calculations.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science > Chemistry | ||||
| Journal or Publication Title: | Chemical Communications | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1359-7345 | ||||
| Official Date: | February 2013 | ||||
| Dates: |
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| Volume: | Volume 49 | ||||
| Number: | Number 25 | ||||
| Page Range: | pp. 2509-2511 | ||||
| DOI: | 10.1039/c3cc36159d | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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