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Boron doped diamond ultramicroelectrodes : a generic platform for sensing single nanoparticle electrocatalytic collisions

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Wakerley, David, Guell, Aleix G., Hutton, Laura A., Miller, Thomas S., Bard, Allen J. and Macpherson, Julie V. (2013) Boron doped diamond ultramicroelectrodes : a generic platform for sensing single nanoparticle electrocatalytic collisions. Chemical Communications, Volume 49 (Number 50). pp. 5657-5659. doi:10.1039/c3cc42915f ISSN 1359-7345.

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Official URL: http://dx.doi.org/10.1039/C3CC42915F

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Abstract

Boron doped diamond (BDD) disk ultramicroelectrodes have been used to sense single nanoparticle (NP) electrocatalytic collision events. BDD serves as an excellent support electrode due to its electrocatalytic inactivity and low background currents and thus can be used to detect the electroactivity of a wide range of colliding NPs, with high sensitivity. In particular, single NP collisions for hydrazine oxidation at Au and Pt NPs were shown to be markedly different.

Item Type: Journal Article
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Journal or Publication Title: Chemical Communications
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Official Date: 2013
Dates:
DateEvent
2013Published
Volume: Volume 49
Number: Number 50
Page Range: pp. 5657-5659
DOI: 10.1039/c3cc42915f
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access

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