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Nanostructures from self-assembling triazine tertiary amine N-oxide amphiphiles
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Beecham, Matthew P., Clarkson, Guy J., Hall, Gareth and Marsh, Andrew (2013) Nanostructures from self-assembling triazine tertiary amine N-oxide amphiphiles. ChemPhysChem, Volume 14 (Number 17). pp. 3909-3915. doi:10.1002/cphc.201300775
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WRAP_Marsh_Self-Assembling Amphiphiles_Accepted_Final.pdf - Accepted Version Download (9Mb) | Preview |
Official URL: http://dx.doi.org/10.1002/cphc.201300775
Abstract
A new set of amphiphilic tertiary amine N-oxides has been prepared and their self-assembly properties observed in aqueous solution by tensiometry, dynamic and static light scattering. X-ray crystallographic analysis of parent amines and sulfoxide congeners indicates the formation of hydrogen bonded dimers as the primary assembly unit for formation of vesicles in preference to the compact micelles typical of lauryl dimethylamine N-oxide (LDAO). 6-Benzyloxy-N,N'-bis(5-diethylaminopentylamine oxide)[1,3,5]triazine-2,4-diamine forms a 1 μm vesicle observed to entrap fluorescein. The [1,3,5]triazine core thus allows variation of the new self-assembled structures from nano- to micrometre length scales.
| Item Type: | Journal Article | ||||
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| Subjects: | Q Science > QD Chemistry T Technology > TP Chemical technology |
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| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Methylamines, Amphiphiles, Nanostructures , Hydrogen bonding, Protein folding | ||||
| Journal or Publication Title: | ChemPhysChem | ||||
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
| ISSN: | 1439-4235 | ||||
| Official Date: | 2 December 2013 | ||||
| Dates: |
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| Volume: | Volume 14 | ||||
| Number: | Number 17 | ||||
| Page Range: | pp. 3909-3915 | ||||
| DOI: | 10.1002/cphc.201300775 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Engineering and Physical Sciences Research Council (EPSRC) |
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