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Formation of 1,3-cyclohexanediones and resorcinols catalyzed by a widely occuring ketosynthase
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Fuchs, Sebastian W., Bozhüyük, Kenan A. J., Kresovic, Darko, Grundmann, Florian, Dill, Veronica, Brachmann, Alexander O., Waterfield, Nicholas R. and Bode, Helge B. (2013) Formation of 1,3-cyclohexanediones and resorcinols catalyzed by a widely occuring ketosynthase. Angewandte Chemie International Edition, Volume 52 (Number 15). pp. 4108-4112. doi:10.1002/anie.201210116 ISSN 1433-7851.
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Official URL: http://dx.doi.org/10.1002/anie.201210116
Abstract
Overlooked, but widespread! A new class of ketosynthases (DarB) involved in the biosynthesis of 1,3-cyclohexanediones and dialkylresorcinols has been identified and characterized in detail. The presence of homologues in 89 different bacteria, including several pathogens, reveals that DarB as well as the corresponding natural products might be widespread, thus presenting a new but so far overlooked pathway to natural products.
Item Type: | Journal Article | ||||
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Divisions: | Faculty of Science, Engineering and Medicine > Medicine > Warwick Medical School > Biomedical Sciences > Microbiology & Infection Faculty of Science, Engineering and Medicine > Medicine > Warwick Medical School |
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Journal or Publication Title: | Angewandte Chemie International Edition | ||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
ISSN: | 1433-7851 | ||||
Official Date: | 2013 | ||||
Dates: |
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Volume: | Volume 52 | ||||
Number: | Number 15 | ||||
Page Range: | pp. 4108-4112 | ||||
DOI: | 10.1002/anie.201210116 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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