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“Magic” surface clustering of borazines driven by repulsive intermolecular forces
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Kervyn, Simon, Kalashnyk, Nataliya, Riello, Massimo, Moreton, Ben, Tasseroul, Jonathan, Wouters, Johan, Jones, T. S. (Tim S.), De Vita, Alessandro, Costantini, Giovanni and Bonifazi, D. (2013) “Magic” surface clustering of borazines driven by repulsive intermolecular forces. Angewandte Chemie International Edition, Volume 52 (Number 29). pp. 7410-7414. doi:10.1002/anie.201300948
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Official URL: http://dx.doi.org/10.1002/anie.201300948
Abstract
It's a kind of magic: Hydroxy pentaaryl borazine molecules self-assemble into small clusters (see structure) on Cu(111) surfaces, whereas with symmetric hexaaryl borazine molecules large islands are obtained. Simulations indicate that the observed “magic” cluster sizes result from long-range repulsive Coulomb forces arising from the deprotonation of the B[BOND]OH groups of the hydroxy pentaaryl borazine.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Intermolecular forces, Inorganic cyclic compounds, Microclusters | ||||
| Journal or Publication Title: | Angewandte Chemie International Edition | ||||
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
| ISSN: | 1433-7851 | ||||
| Official Date: | 2013 | ||||
| Dates: |
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| Volume: | Volume 52 | ||||
| Number: | Number 29 | ||||
| Page Range: | pp. 7410-7414 | ||||
| DOI: | 10.1002/anie.201300948 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | European Union (EU), Fonds national de la recherche scientifique (Belgium) (FNRS), Belgium. Politique scientifique fédérale, Italy. Ministero dell'istruzione, dell'università e della ricerca (MIUR), Université de Namur, Engineering and Physical Sciences Research Council (EPSRC), Royal Society (Great Britain), University of Warwick |
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