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Spectroscopic signatures of an Fmoc–tetrapeptide, Fmoc and fluorene
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Zou, Yi, Razmkhah, Kasra, Chmel, Nikola Paul, Hamley, Ian W. and Rodger, Alison (2013) Spectroscopic signatures of an Fmoc–tetrapeptide, Fmoc and fluorene. RSC Advances , Volume 3 (Number 27). pp. 10854-10858. doi:10.1039/c3ra41979g ISSN 2046-2069.
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Official URL: http://dx.doi.org/10.1039/c3ra41979g
Abstract
The hydrophobic Fmoc [N-(fluorenyl)-9-methoxycarbonyl] unit is often conjugated to peptides to confer amphiphilicity on the molecules, and to introduce the potential for aromatic stacking interactions. In this paper we report spectroscopic data for fluorene, Fmoc and Fmoc conjugated to a small peptide (GRDS in this case) to enable interpretation of spectroscopic data collected on complex structures that can be created with Fmoc-peptide molecules. We report absorbance data (ultra violet and infrared), circular dichroism, linear dichroism (both film and Couette flow orientation) and Raman spectra. Orientations of the Fmoc chromophores in the linear dichroism studies are deduced.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Journal or Publication Title: | RSC Advances | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 2046-2069 | ||||
| Official Date: | 8 May 2013 | ||||
| Dates: |
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| Volume: | Volume 3 | ||||
| Number: | Number 27 | ||||
| Page Range: | pp. 10854-10858 | ||||
| DOI: | 10.1039/c3ra41979g | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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