The Library
Dual-barrel conductance micropipet as a new approach to the study of ionic crystal dissolution kinetics
Tools
Kinnear, Sophie L., McKelvey, Kim M. (Kim Martin), Snowden, Michael E., Peruffo, Massimo, Colburn, Alex W. and Unwin, Patrick R. (2013) Dual-barrel conductance micropipet as a new approach to the study of ionic crystal dissolution kinetics. Langmuir, Volume 29 (Number 50). pp. 15565-15572. doi:10.1021/la403630u ISSN 0743-7463.
|
PDF
WRAP_1050272-ch-270515-nacl_dissolution.pdf - Accepted Version - Requires a PDF viewer. Download (1702Kb) | Preview |
Official URL: http://dx.doi.org/10.1021/la403630u
Abstract
A new approach to the study of ionic crystal dissolution kinetics is described, based on the use of a dual-barrel theta conductance micropipet. The solution in the pipet is undersaturated with respect to the crystal of interest, and when the meniscus at the end of the micropipet makes contact with a selected region of the crystal surface, dissolution occurs causing the solution composition to change. This is observed, with better than 1 ms time resolution, as a change in the ion conductance current, measured across a potential bias between an electrode in each barrel of the pipet. Key attributes of this new technique are: (i) dissolution can be targeted at a single crystal surface; (ii) multiple measurements can be made quickly and easily by moving the pipet to a new location on the surface; (iii) materials with a wide range of kinetics and solubilities are open to study because the duration of dissolution is controlled by the meniscus contact time; (iv) fast kinetics are readily amenable to study because of the intrinsically high mass transport rates within tapered micropipets; (v) the experimental geometry is well-defined, permitting finite element method modeling to allow quantitative analysis of experimental data. Herein, we study the dissolution of NaCl as an example system, with dissolution induced for just a few milliseconds, and estimate a first-order heterogeneous rate constant of 7.5 (±2.5) × 10–5 cm s–1 (equivalent surface dissolution flux ca. 0.5 μmol cm–2 s–1 into a completely undersaturated solution). Ionic crystals form a huge class of materials whose dissolution properties are of considerable interest, and we thus anticipate that this new localized microscale surface approach will have considerable applicability in the future.
Item Type: | Journal Article | ||||||||
---|---|---|---|---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||
Library of Congress Subject Headings (LCSH): | Micropipettes, Ionic crystals, Equilibrium, Ionic | ||||||||
Journal or Publication Title: | Langmuir | ||||||||
Publisher: | American Chemical Society | ||||||||
ISSN: | 0743-7463 | ||||||||
Official Date: | 13 November 2013 | ||||||||
Dates: |
|
||||||||
Volume: | Volume 29 | ||||||||
Number: | Number 50 | ||||||||
Number of Pages: | 8 | ||||||||
Page Range: | pp. 15565-15572 | ||||||||
DOI: | 10.1021/la403630u | ||||||||
Status: | Peer Reviewed | ||||||||
Publication Status: | Published | ||||||||
Access rights to Published version: | Restricted or Subscription Access | ||||||||
Date of first compliant deposit: | 26 December 2015 | ||||||||
Date of first compliant Open Access: | 26 December 2015 | ||||||||
Funder: | European Research Council (ERC), European Commission (EC), Seventh Framework Programme (European Commission) (FP7), Engineering and Physical Sciences Research Council (EPSRC), Advantage West Midlands (AWM), European Regional Development Fund (ERDF) | ||||||||
Grant number: | ERC-2009-AdG2471143-QUANTIF (FP7) |
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |
Downloads
Downloads per month over past year