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Synthesis, structures and properties of a family of four two-dimensional coordination polymers constructed from 5-hydroxyisophthalate
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Zhang, Kou-Lin, Zhang, Jing-Bo, Jing, Chu-Yue, Zhang, Lei, Walton, Richard I., Zhu, Peizhi and Ng, Seik Weng (2014) Synthesis, structures and properties of a family of four two-dimensional coordination polymers constructed from 5-hydroxyisophthalate. Journal of Solid State Chemistry, Volume 211 . pp. 8-20. doi:10.1016/j.jssc.2013.12.005
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Official URL: http://dx.doi.org/10.1016/j.jssc.2013.12.005
Abstract
Four 2D coordination polymers (CPs) with different structures containing the multifunctional ligand 5-hydroxyisophthalate (5-OH-BDC2−), [Zn(5-OH-BDC)(btb)]·2H2O (1), [Cd(5-OH-BDC)(btp)(H2O)]·3H2O (2), [Cd(5-OH-BDC)(bth)2(H2O)]·H2O (3) and [Pb(5-OH-BDC)]·H2O (4) [btp=1, 3-bis(1,2,4-triazol-1-yl)propane, btb=1,4-bis(1,2,4-triazol-1-yl)butane, bth=1, 6-bis(1,2,4-triazol-1-yl)hexane] were obtained. 1–3 were synthesised hydrothermally, while 4 was obtained under ambient condition. The adjacent (2D→2D) polycatenated 2D layers of 1 polythread in a parallel manner to form an unusual 2D→3D polythreaded framework. 2 contains an undulated 2D (4, 4) network and further extends into an “embracing” double-layer structure through the C–H···π and π···π stacking interactions. 3 exhibits a non-interpenetrating 2D (4, 4)-network. 4 exhibits a 2D double-layered binodal (4, 4)-net containing oblong nanochannels with symbol (4363)2. Reversible dehydration–rehydration is observed in 1, 2 and 4, which fall within the category of “recoverable collapsing” and “guest-induced re-formation” frameworks, while 3 exhibits irreversible dehydration–rehydration behaviour. The solid state fluorescent properties of 1–4 have been investigated.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Journal or Publication Title: | Journal of Solid State Chemistry | ||||
| Publisher: | Academic Press | ||||
| ISSN: | 0022-4596 | ||||
| Official Date: | 2014 | ||||
| Dates: |
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| Volume: | Volume 211 | ||||
| Page Range: | pp. 8-20 | ||||
| DOI: | 10.1016/j.jssc.2013.12.005 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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