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Photochemical control of molecular motion associated with pyramidal inversion

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Hough, Alexander J., Prokes, Ivan, Tucker, James H. R., Shipman, Michael and Walsh, Tiffany R. (2013) Photochemical control of molecular motion associated with pyramidal inversion. Chemical Communications, Volume 49 (Number 59). pp. 6683-6685. doi:10.1039/c3cc43036g

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Official URL: http://dx.doi.org/10.1039/C3CC43036G

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Abstract

Rates of pyramidal motion in an aziridine are controlled by reversible trans to cis photoisomerisation of an azobenzene unit attached to the ring nitrogen atom. The dynamics of the inversion process and activation parameters are derived by variable temperature NMR, and are supported by ab initio calculations.

Item Type: Journal Article
Divisions: Faculty of Science > Chemistry
Journal or Publication Title: Chemical Communications
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Official Date: 7 June 2013
Dates:
DateEvent
7 June 2013Published
Volume: Volume 49
Number: Number 59
Page Range: pp. 6683-6685
DOI: 10.1039/c3cc43036g
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access

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