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Photochemical control of molecular motion associated with pyramidal inversion
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Hough, Alexander J., Prokes, Ivan, Tucker, James H. R., Shipman, Michael and Walsh, Tiffany R. (2013) Photochemical control of molecular motion associated with pyramidal inversion. Chemical Communications, Volume 49 (Number 59). pp. 6683-6685. doi:10.1039/c3cc43036g
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Official URL: http://dx.doi.org/10.1039/C3CC43036G
Abstract
Rates of pyramidal motion in an aziridine are controlled by reversible trans to cis photoisomerisation of an azobenzene unit attached to the ring nitrogen atom. The dynamics of the inversion process and activation parameters are derived by variable temperature NMR, and are supported by ab initio calculations.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science > Chemistry | ||||
| Journal or Publication Title: | Chemical Communications | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1359-7345 | ||||
| Official Date: | 7 June 2013 | ||||
| Dates: |
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| Volume: | Volume 49 | ||||
| Number: | Number 59 | ||||
| Page Range: | pp. 6683-6685 | ||||
| DOI: | 10.1039/c3cc43036g | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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