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Dissociation and hierarchical assembly of chiral esters on metallic surfaces
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Moreton, Ben, Fang, Zhijia (Researcher in chemistry), Wills, Martin and Costantini, Giovanni (2013) Dissociation and hierarchical assembly of chiral esters on metallic surfaces. Chemical Communications, 49 (58). pp. 6477-6479. doi:10.1039/c3cc40805a ISSN 1359-7345.
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WRAP_574780-ch-280915-costantini_-_manuscript_post_print__chem._commun._2013_49_6477-6479.pdf - Accepted Version - Requires a PDF viewer. Download (471Kb) | Preview |
Official URL: http://dx.doi.org/10.1039/C3CC40805A
Abstract
The interaction of a de novo synthesised ester with single crystal metal surfaces has been investigated as a model system for the heterogeneous hydrogenolysis of esters. Scanning tunnelling microscopy measurements show dissociative adsorption at room temperature on Cu(110) but no significant reaction on Au(111). The dissociative pathway has been identified by comparing with possible fragment species, demonstrating that the ester cleavage occurs along the RCH(CH3)–OC(O)R bond.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Esters, Chirality | ||||
Journal or Publication Title: | Chemical Communications | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 2013 | ||||
Dates: |
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Volume: | 49 | ||||
Number: | 58 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 6477-6479 | ||||
DOI: | 10.1039/c3cc40805a | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Date of first compliant deposit: | 26 December 2015 | ||||
Date of first compliant Open Access: | 26 December 2015 | ||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), Royal Society (Great Britain), University of Warwick, Birmingham Science City, Advantage West Midlands (AWM) | ||||
Grant number: | EP/G044864/1 (EPSRC), RG100917 (RS), |
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