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Poly(acrylates) via SET-LRP in a continuous tubular reactor

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Burns, James A., Houben, Claudia, Anastasaki, Athina, Waldron, Christopher, Lapkin, Alexei and Haddleton, David M. (2013) Poly(acrylates) via SET-LRP in a continuous tubular reactor. Polymer Chemistry, Volume 4 (Number 17). pp. 4809-4813. doi:10.1039/c3py00833a

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Official URL: http://dx.doi.org/10.1039/c3py00833a

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Abstract

A simple, easy to construct, bench-top plug flow reactor consisting of PTFE tubing with a Cu(0) threaded core (wire) was used to perform SET-LRP of methyl acrylate. The reaction was optimized by changing the residence time within the flow reactor. Both changing the flow reactor length and changing the flow rate was seen to control the resultant polymer molecular weight. Using a 20 cm reactor length, 95% conversion of monomer was seen at a flow rate of 0.1 mL min-1. The polymers formed had narrow molecular weight distributions (PDI< 1.2), and very high ω-chain end fidelity, as seen by both 1H NMR and MALDI-TOF MS.

Item Type: Journal Article
Divisions: Faculty of Science > Chemistry
Journal or Publication Title: Polymer Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1759-9954
Official Date: 2013
Dates:
DateEvent
2013Published
Volume: Volume 4
Number: Number 17
Page Range: pp. 4809-4813
DOI: 10.1039/c3py00833a
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Open Access

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