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Poly(acrylates) via SET-LRP in a continuous tubular reactor
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Burns, James A. (James Adam), Houben, Claudia, Anastasaki, Athina, Waldron, Christopher, Lapkin, Alexei and Haddleton, David M. (2013) Poly(acrylates) via SET-LRP in a continuous tubular reactor. Polymer Chemistry, Volume 4 (Number 17). pp. 4809-4813. doi:10.1039/c3py00833a
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Official URL: http://dx.doi.org/10.1039/c3py00833a
Abstract
A simple, easy to construct, bench-top plug flow reactor consisting of PTFE tubing with a Cu(0) threaded core (wire) was used to perform SET-LRP of methyl acrylate. The reaction was optimized by changing the residence time within the flow reactor. Both changing the flow reactor length and changing the flow rate was seen to control the resultant polymer molecular weight. Using a 20 cm reactor length, 95% conversion of monomer was seen at a flow rate of 0.1 mL min-1. The polymers formed had narrow molecular weight distributions (PDI< 1.2), and very high ω-chain end fidelity, as seen by both 1H NMR and MALDI-TOF MS.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science > Chemistry | ||||
| Journal or Publication Title: | Polymer Chemistry | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1759-9954 | ||||
| Official Date: | 2013 | ||||
| Dates: |
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| Volume: | Volume 4 | ||||
| Number: | Number 17 | ||||
| Page Range: | pp. 4809-4813 | ||||
| DOI: | 10.1039/c3py00833a | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Open Access |
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