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Competing πσ* states in the photodissociation of adenine
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Wells, Kym L., Hadden, David J., Nix, Michael G. D. and Stavros, Vasilios G. (2010) Competing πσ* states in the photodissociation of adenine. Journal of Physical Chemistry Letters, Vol.1 (No.6). pp. 993-996. doi:10.1021/jz100050y ISSN 1948-7185.
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Official URL: http://dx.doi.org/10.1021/jz100050y
Abstract
Despite the extensive investigations thus far, there is still debate regarding the role of the repulsive pi sigma* state in the photochemistry of adenine. We present evidence that suggests that H-atom elimination via both the azole group (N-9) and the often overlooked amino group (N-6) occurs following excitation at 200 nm. In contrast, excitation at 266 nm supports the view that the role of the pi sigma* states is minimal.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Photodissociation, Molecular dynamics, Adenine | ||||
Journal or Publication Title: | Journal of Physical Chemistry Letters | ||||
Publisher: | American Chemical Society | ||||
ISSN: | 1948-7185 | ||||
Official Date: | 18 March 2010 | ||||
Dates: |
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Volume: | Vol.1 | ||||
Number: | No.6 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 993-996 | ||||
DOI: | 10.1021/jz100050y | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Funder: | University of Warwick, Engineering and Physical Sciences Research Council (EPSRC), Royal Society (Great Britain) | ||||
Grant number: | EP/E011187 (EPSRC) |
Data sourced from Thomson Reuters' Web of Knowledge
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