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Competing πσ* states in the photodissociation of adenine
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Wells, Kym L., Hadden, David J., Nix, Michael G. D. and Stavros, Vasilios G.. (2010) Competing πσ* states in the photodissociation of adenine. Journal of Physical Chemistry Letters, Vol.1 (No.6). pp. 993-996. ISSN 1948-7185
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Official URL: http://dx.doi.org/10.1021/jz100050y
Abstract
Despite the extensive investigations thus far, there is still debate regarding the role of the repulsive pi sigma* state in the photochemistry of adenine. We present evidence that suggests that H-atom elimination via both the azole group (N-9) and the often overlooked amino group (N-6) occurs following excitation at 200 nm. In contrast, excitation at 266 nm supports the view that the role of the pi sigma* states is minimal.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Chemistry |
| Library of Congress Subject Headings (LCSH): | Photodissociation, Molecular dynamics, Adenine |
| Journal or Publication Title: | Journal of Physical Chemistry Letters |
| Publisher: | American Chemical Society |
| ISSN: | 1948-7185 |
| Date: | 18 March 2010 |
| Volume: | Vol.1 |
| Number: | No.6 |
| Number of Pages: | 4 |
| Page Range: | pp. 993-996 |
| Identification Number: | 10.1021/jz100050y |
| Status: | Peer Reviewed |
| Publication Status: | Published |
| Access rights to Published version: | Restricted or Subscription Access |
| Funder: | University of Warwick, Engineering and Physical Sciences Research Council (EPSRC), Royal Society (Great Britain) |
| Grant number: | EP/E011187 (EPSRC) |
| URI: | http://wrap.warwick.ac.uk/id/eprint/6029 |
Data sourced from Thomson Reuters' Web of Knowledge
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