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Spectroscopic and computational study of ligand photodissociation from [Ru(dipyrido[3,2-a:2',3'-c]phenazine)(4-aminopyridine)(4)](2+)
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Ruiu, Tiziana, Garino, Claudio, Salassa, Luca, Pizarro, Ana M., Nervi, Carlo, Gobetto, Roberto and Sadler, P. J. (2010) Spectroscopic and computational study of ligand photodissociation from [Ru(dipyrido[3,2-a:2',3'-c]phenazine)(4-aminopyridine)(4)](2+). European Journal of Inorganic Chemistry, Vol.2010 (No.8). pp. 1186-1195. doi:10.1002/ejic.200900990
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Official URL: http://dx.doi.org/10.1002/ejic.200900990
Abstract
The new complex [Ru(dppz)(4AP)(4)](2+) (1, in which dppz = dipyrido[3,2-a:2',3'-c]phenazine and 4AP = 4-aminopyridine) has been synthesized, characterized and its photophysical and photochemical properties have been studied by combining spectroscopic and computational [DFT and time-dependent (TD) DFT] methods. Upon irradiation in aqueous solution, complex I selectively photoreleases one 4AP ligand and subsequently coordinates a water molecule to form [Ru(dppz)(4AP)(3)(OH2)](2+).
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Photochemistry, Ruthenium, Density functionals, Ligands, Coordination compounds | ||||
| Journal or Publication Title: | European Journal of Inorganic Chemistry | ||||
| Publisher: | Wiley-VCH Verlag GMBH | ||||
| ISSN: | 1434-1948 | ||||
| Official Date: | March 2010 | ||||
| Dates: |
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| Volume: | Vol.2010 | ||||
| Number: | No.8 | ||||
| Number of Pages: | 10 | ||||
| Page Range: | pp. 1186-1195 | ||||
| DOI: | 10.1002/ejic.200900990 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Piedmont (Italy), Seventh Framework Programme (European Commission) (FP7), Medical Research Council (Great Britain) (MRC), European Regional Development Fund (ERDF), Advantage West Midlands (AWM) | ||||
| Grant number: | 220281 (FP7) |
Data sourced from Thomson Reuters' Web of Knowledge
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