Ruiu, Tiziana, Garino, Claudio, Salassa, Luca, Pizarro, Ana M., Nervi, Carlo, Gobetto, Roberto and Sadler, P. J.. (2010) Spectroscopic and computational study of ligand photodissociation from [Ru(dipyrido[3,2-a:2',3'-c]phenazine)(4-aminopyridine)(4)](2+). European Journal of Inorganic Chemistry, Vol.2010 (No.8). pp. 1186-1195. ISSN 1434-1948

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Abstract

The new complex [Ru(dppz)(4AP)(4)](2+) (1, in which dppz = dipyrido[3,2-a:2',3'-c]phenazine and 4AP = 4-aminopyridine) has been synthesized, characterized and its photophysical and photochemical properties have been studied by combining spectroscopic and computational [DFT and time-dependent (TD) DFT] methods. Upon irradiation in aqueous solution, complex I selectively photoreleases one 4AP ligand and subsequently coordinates a water molecule to form [Ru(dppz)(4AP)(3)(OH2)](2+).

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Photochemistry, Ruthenium, Density functionals, Ligands, Coordination compounds
Journal or Publication Title:	European Journal of Inorganic Chemistry
Publisher:	Wiley-VCH Verlag GMBH
ISSN:	1434-1948
Date:	March 2010
Volume:	Vol.2010
Number:	No.8
Number of Pages:	10
Page Range:	pp. 1186-1195
Identification Number:	10.1002/ejic.200900990
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Piedmont (Italy), Seventh Framework Programme (European Commission) (FP7), Medical Research Council (Great Britain) (MRC), European Regional Development Fund (ERDF), Advantage West Midlands (AWM)
Grant number:	220281 (FP7)
URI:	http://wrap.warwick.ac.uk/id/eprint/6201

Data sourced from Thomson Reuters' Web of Knowledge

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