Skip to content Skip to navigation
University of Warwick
  • Study
  • |
  • Research
  • |
  • Business
  • |
  • Alumni
  • |
  • News
  • |
  • About

University of Warwick
Publications service & WRAP

Highlight your research

  • WRAP
    • Home
    • Search WRAP
    • Browse by Warwick Author
    • Browse WRAP by Year
    • Browse WRAP by Subject
    • Browse WRAP by Department
    • Browse WRAP by Funder
    • Browse Theses by Department
  • Publications Service
    • Home
    • Search Publications Service
    • Browse by Warwick Author
    • Browse Publications service by Year
    • Browse Publications service by Subject
    • Browse Publications service by Department
    • Browse Publications service by Funder
  • Help & Advice
University of Warwick

The Library

  • Login
  • Admin

A multispectroscopic structural study of lead silicate glasses over an extended range of compositions

Tools
- Tools
+ Tools

Feller, S., Lodden, G., Riley, A., Edwards, T., Croskrey, J., Schue, A., Liss, D., Stentz, D., Blair, S., Kelley, M., Smith, G., Singleton, S., Affatigato, M., Holland, Diane, Smith, Mark E., Kamitsos, E. I., Varsamis, C. P. E. and Ioannou, E. (2010) A multispectroscopic structural study of lead silicate glasses over an extended range of compositions. Journal of Non-Crystalline Solids, Vol.356 (No.6-8). pp. 304-313. doi:10.1016/j.jnoncrysol.2009.12.003 ISSN 0022-3093.

Research output not available from this repository.

Request-a-Copy directly from author or use local Library Get it For Me service.

Official URL: http://dx.doi.org/10.1016/j.jnoncrysol.2009.12.003

Request Changes to record.

Abstract

A series of lead silicate glasses, spanning the broadest reported range of lead contents (up to 83 mol% PbO), were prepared, on which the following spectroscopic observations were made: Si-29 magic angle spinning nuclear magnetic resonance, time of flight mass spectroscopy, raman spectroscopy and fourier transform infrared spectroscopy. For bulk. splat-quenched samples, infrared results indicate that the lever rule is approximately followed until about 60 mol% PbO, though with considerable dissociation of the stoichiometric groups into silicate units with lesser and greater numbers of non-bridging oxygens. For roller-quenched samples, nuclear magnetic resonance data are consistent with a statistical distribution up to this lead concentration. Above 60 mol% PbO, added oxygen remains associated with lead to form a separate lead oxide glass network. The evidence for this comes from each of the spectroscopic techniques employed. A quantitative distribution of PbO is given. (C) 2009 Elsevier B.V. All rights reserved.

Item Type: Journal Article
Subjects: T Technology > TP Chemical technology
T Technology > TA Engineering (General). Civil engineering (General)
Divisions: Faculty of Science, Engineering and Medicine > Science > Physics
Journal or Publication Title: Journal of Non-Crystalline Solids
Publisher: Elsevier Science BV
ISSN: 0022-3093
Official Date: 1 March 2010
Dates:
DateEvent
1 March 2010Published
Volume: Vol.356
Number: No.6-8
Number of Pages: 10
Page Range: pp. 304-313
DOI: 10.1016/j.jnoncrysol.2009.12.003
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: National Science Foundation (U.S.) (NSF), Engineering and Physical Sciences Research Council (EPSRC), INCO
Grant number: DMR 0211718, DMR 05020518, CERAMED-ICA3-CT-2002-10018

Data sourced from Thomson Reuters' Web of Knowledge

Request changes or add full text files to a record

Repository staff actions (login required)

View Item View Item
twitter

Email us: wrap@warwick.ac.uk
Contact Details
About Us