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Thermodynamics of 4,4′-stilbenedicarboxylic acid monolayer self-assembly at the nonanoic acid–graphite interface

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Song, Wentao, Martsinovich, Natalia, Heckl, Wolfgang M. and Lackinger, Markus (2014) Thermodynamics of 4,4′-stilbenedicarboxylic acid monolayer self-assembly at the nonanoic acid–graphite interface. Physical Chemistry Chemical Physics, Volume 16 (Number 26). pp. 13239-13247. doi:10.1039/c4cp01147c

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Official URL: http://dx.doi.org/10.1039/C4CP01147C

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Abstract

A direct calorimetric measurement of the overall enthalpy change associated with self-assembly of organic monolayers at the liquid–solid interface is for most systems of interest practically impossible. In previous work we proposed an adapted Born–Haber cycle for an indirect assessment of the overall enthalpy change by using terephthalic acid monolayers at the nonanoic acid–graphite interface as a model system. To this end, the sublimation enthalpy, dissolution enthalpy, the monolayer binding enthalpy in vacuum, and a dewetting enthalpy are combined to yield the total enthalpy change. In the present study the Born–Haber cycle is applied to 4,4′-stilbenedicarboxylic acid monolayers. A detailed comparison of these two aromatic dicarboxylic acids is used to evaluate and quantify the contribution of the organic backbone for stabilization of the monolayer at the nonanoic acid–graphite interface.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Faculty of Science, Engineering and Medicine > Science > Centre for Scientific Computing
Library of Congress Subject Headings (LCSH): Carboxylic acids, Nanotechnology
Journal or Publication Title: Physical Chemistry Chemical Physics
Publisher: Royal Society of Chemistry
ISSN: 1463-9076
Official Date: 2014
Dates:
DateEvent
2014Published
14 May 2014Available
14 May 2014Accepted
17 March 2014Submitted
Volume: Volume 16
Number: Number 26
Number of Pages: 9
Page Range: pp. 13239-13247
DOI: 10.1039/c4cp01147c
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Open Access
Funder: China Scholarship Council (CSC), Nanosystems Initiative Munich (NIM)

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