
The Library
Copper(I) halide mediated tandem 1,4-aryl migration-oxidative amidyl radical cyclisation of bromosulfonamides
Tools
Clark, Andrew J., Fullaway, David R., Murphy, Nicholas P. and Parekh, Hemal (2010) Copper(I) halide mediated tandem 1,4-aryl migration-oxidative amidyl radical cyclisation of bromosulfonamides. Synlett (No.4). pp. 610-614. doi:10.1055/S-0029-1219151 ISSN 0936-5214.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1055/s-0029-1219151
Abstract
Reaction of N-butyl-N-(2-bromo-2-methylpropionyl)-arylsulfonamides with CuBr/tripyridylamine leads to amidyl radicals via 1,4-aryl migration with concomitant loss of SO2, which can further undergo cyclisation to oxindoles or reduction to amides with the ratio dependent upon the temperature and solvent utilised.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Copper, Free radical reactions, Ring formation (Chemistry), Sulfonamides | ||||
Journal or Publication Title: | Synlett | ||||
Publisher: | Georg Thieme Verlag | ||||
ISSN: | 0936-5214 | ||||
Official Date: | March 2010 | ||||
Dates: |
|
||||
Number: | No.4 | ||||
Number of Pages: | 5 | ||||
Page Range: | pp. 610-614 | ||||
DOI: | 10.1055/S-0029-1219151 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC) | ||||
Grant number: | EP/F016573 (EPSRC) |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
![]() |
View Item |