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Synthesis of symmetrical, substituted (alkane-α,ω-diyl)(bis[3,3′-allyl dithioethers]) monomers for photoplastic polymer networks
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Moorhoff, Cornelis M., Cook, Wayne D., Schiller, Tara L., Braybrook, Carl and Thang, San H. (2012) Synthesis of symmetrical, substituted (alkane-α,ω-diyl)(bis[3,3′-allyl dithioethers]) monomers for photoplastic polymer networks. Australian Journal of Chemistry, Volume 65 (Number 8). p. 1165. doi:10.1071/CH12278 ISSN 0004-9425.
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Official URL: http://dx.doi.org/10.1071/CH12278
Abstract
Novel symmetrical (alkane-α,ω-diyl)(bis[3,3′-allyl dithioethers]) compounds and their ether analogues, have been synthesised from (alkane-α,ω-diyl)bis([2-{chloromethyl}allyl]sulfane) precursors, for use in crosslinked polymers which exhibit photoplastic behaviour. Facile synthesis and purification of these monomers was achieved if the alkane-α,ω-diyl moiety had at least one oxygen atom in this linker. The number of sulfur atoms in these monomers was varied from four to two to zero to produce monomers which can be used to evaluate their importance on the photoplasticity behaviour.
Item Type: | Journal Article | ||||
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Divisions: | Faculty of Science, Engineering and Medicine > Engineering > WMG (Formerly the Warwick Manufacturing Group) | ||||
Journal or Publication Title: | Australian Journal of Chemistry | ||||
Publisher: | CSIRO Publishing | ||||
ISSN: | 0004-9425 | ||||
Official Date: | 8 August 2012 | ||||
Dates: |
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Volume: | Volume 65 | ||||
Number: | Number 8 | ||||
Page Range: | p. 1165 | ||||
DOI: | 10.1071/CH12278 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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