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Synthesis and catalytic applications of an extended range of tethered ruthenium(II)/η6-Arene/diamine complexes
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Hodgkinson, Roy, Jurčík, Václav, Zanotti-Gerosa, Antonio, Nedden, Hans Günter, Blackaby, Andrew, Clarkson, Guy J. and Wills, Martin (2014) Synthesis and catalytic applications of an extended range of tethered ruthenium(II)/η6-Arene/diamine complexes. Organometallics, Volume 33 (Number 19). pp. 5517-5524. doi:10.1021/om500788t ISSN 0276-7333.
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Official URL: http://dx.doi.org/10.1021/om500788t
Abstract
A series of novel enantiopure Ru(II) complexes containing a chiral diamine and η6-arene connected by a tethering group have been prepared and were evaluated in the asymmetric reductions of a range of ketones. Changes to the level of steric hindrance and the addition of an electron-withdrawing functionality on the sulfonyl group have a significant effect on the reactivity and enantioselectivity of the catalysts.
Item Type: | Journal Article | ||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||
Library of Congress Subject Headings (LCSH): | Ruthenium catalysts | ||||||||
Journal or Publication Title: | Organometallics | ||||||||
Publisher: | American Chemical Society | ||||||||
ISSN: | 0276-7333 | ||||||||
Official Date: | 13 October 2014 | ||||||||
Dates: |
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Volume: | Volume 33 | ||||||||
Number: | Number 19 | ||||||||
Number of Pages: | 8 | ||||||||
Page Range: | pp. 5517-5524 | ||||||||
DOI: | 10.1021/om500788t | ||||||||
Status: | Peer Reviewed | ||||||||
Publication Status: | Published | ||||||||
Access rights to Published version: | Restricted or Subscription Access | ||||||||
Date of first compliant deposit: | 15 January 2016 | ||||||||
Date of first compliant Open Access: | 15 January 2016 | ||||||||
Funder: | Technology Strategy Board (Great Britain), Johnson Matthey Plc. | ||||||||
Grant number: | 101330 (TSB) |
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