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Conformation-controlled sorption properties and breathing of the aliphatic Al-MOF [Al(OH)(CDC)]
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Niekiel, Felicitas, Lannoeye, Jeroen, Reinsch, Helge, Munn, Alexis S., Heerwig, Andreas, Zizak, Ivo, Kaskel, Stefan, Walton, Richard I., de Vos, Dirk, Llewellyn, Philip, Lieb, Alexandra, Maurin, Guillaume and Stock, Norbert (2014) Conformation-controlled sorption properties and breathing of the aliphatic Al-MOF [Al(OH)(CDC)]. Inorganic Chemistry, Volume 53 (Number 9). pp. 4610-4620. doi:10.1021/ic500288w ISSN 0020-1669.
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Official URL: http://dx.doi.org/10.1021/ic500288w
Abstract
The sorption properties of the Al-MOF CAU-13 were studied in detail. The adsorption of water and CO2 leads to small structural changes. However, when CAU-13 is exposed to xylene, a drastic change in the crystal structure is observed. In the evacuated form, CAU-13 contains trans-cyclohexanedicarboxylate linkers in the e,e and a,a conformations. After the adsorption of xylene, all of the linker molecules exhibit the e,e conformation, leading to a unit cell increase of ∼25%.
Item Type: | Journal Article | ||||||||
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||
Journal or Publication Title: | Inorganic Chemistry | ||||||||
Publisher: | American Chemical Society | ||||||||
ISSN: | 0020-1669 | ||||||||
Official Date: | 5 May 2014 | ||||||||
Dates: |
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Volume: | Volume 53 | ||||||||
Number: | Number 9 | ||||||||
Page Range: | pp. 4610-4620 | ||||||||
DOI: | 10.1021/ic500288w | ||||||||
Status: | Peer Reviewed | ||||||||
Publication Status: | Published | ||||||||
Access rights to Published version: | Restricted or Subscription Access |
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