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Kinetic and structural studies on 'tethered' Ru(II) arene ketone reduction catalysts

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Cheung, Fung Kei, Clarke, Adam J., Clarkson, Guy J., Fox, D. J. (David J.), Graham, Mark A., Lin, Changxue, Crivillé, Adriana Lorente and Wills, Martin. (2010) Kinetic and structural studies on 'tethered' Ru(II) arene ketone reduction catalysts. Dalton Transactions, Vol.39 (No.5). pp. 1395-1402. ISSN 1477-9226

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Official URL: http://dx.doi.org/10.1039/b915932k

Abstract

A series of kinetic and structural investigations on ruthenium-based catalysts for asymmetric transfer hydrogenation (ATH) of ketones are reported. A method is reported for monitoring the formation of ruthenium hydride species in real time using H-1 NMR spectroscopy.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Catalysts -- Analysis, Ruthenium, Ketones
Journal or Publication Title:	Dalton Transactions
Publisher:	Royal Society of Chemistry
ISSN:	1477-9226
Official Date:	2010
Volume:	Vol.39
Number:	No.5
Number of Pages:	8
Page Range:	pp. 1395-1402
Identification Number:	10.1039/b915932k
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Engineering and Physical Sciences Research Council (EPSRC), AstraZeneca (Firm), British Council
Grant number:	GR/S72214/1 (EPSRC), EP/D072182/1 (EPSRC)
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URI:	http://wrap.warwick.ac.uk/id/eprint/6528