Predictive thermodynamics for condensed phases
UNSPECIFIED (2005) Predictive thermodynamics for condensed phases. CHEMICAL SOCIETY REVIEWS, 34 (10). pp. 866-874. ISSN 0306-0012Full text not available from this repository.
Official URL: http://dx.doi.org/10.1039/b501741f
Thermodynamic information is central to assessment of the stability and reactivity of materials. However, because of both the demanding nature of experimental thermodynamics and the virtually unlimited number of conceivable compounds, experimental data is often unavailable or, for hypothetical materials, necessarily impossible to obtain. We describe simple procedures for thermodynamic prediction for condensed phases, both ionic and organic covalent, principally via formula unit volumes ( or density); our volume-based approach (VBT) provides a new thermodynamic tool for such assessment. These methods, being independent of detailed knowledge of crystal structures, are applicable to liquids and amorphous materials as well as to crystalline solids. Examples of their use are provided.
|Item Type:||Journal Item|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||CHEMICAL SOCIETY REVIEWS|
|Publisher:||ROYAL SOC CHEMISTRY|
|Number of Pages:||9|
|Page Range:||pp. 866-874|
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